67066-09-5

Basic information

• Product Name: 5-Monobromo-10,15,20-triphenylporphine
• Synonyms: 5-Monobromo-10,15,20-triphenylporphine;21H,23H-Porphine, 5-bromo-10,15,20-triphenyl-;5-Bromo-10,15,20-triphenylporphine
• CAS NO: 67066-09-5
• Molecular Formula: C38H25BrN4
• Molecular Weight: 617.5359
• Product Categories: Porphyrins
• Mol File: 67066-09-5.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-Monobromo-10,15,20-triphenylporphine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Monobromo-10,15,20-triphenylporphine(67066-09-5)
• EPA Substance Registry System: 5-Monobromo-10,15,20-triphenylporphine(67066-09-5)

Safety Data

• Hazardous Substances Data: 67066-09-5(Hazardous Substances Data)

Usage

General Description

5-Monobromo-10,15,20-triphenylporphine, also known as TBPP, is a chemical compound that belongs to the class of porphyrins. It is a type of organometallic compound that contains a central metal ion coordinated to a porphyrin ligand. TBPP consists of three phenyl rings attached to a central porphyrin ring, and it also contains a bromine atom in one of the positions on the porphyrin ring. 5-Monobromo-10,15,20-triphenylporphine has potential applications in various fields such as catalysis, photodynamic therapy, and as a ligand in coordination chemistry. It is important in the development of new materials and the study of porphyrin-based systems for various applications.

Upstream product

• 21211-65-4 di(pyrrol-2-yl)methane 
• 100-52-7 benzaldehyde 
• 591-51-5 phenyllithium 
• 22112-89-6 5,15-diphenylporphyrin 

Downstream Products

• 133513-04-9 5-(3-bromophenyl)-10,15,20-triphenylporphyrin 
• 133513-02-7 10-(4-chlorophenyl)-5,15,20-triphenylporphyrin 
• 130557-52-7 5-(m-cyanophenyl)-10,15,20-triphenylporphyrin 
• 123444-61-1 5-(p-formylphenyl)-10,15,20-triphenylporphyrin 
• 87345-22-0 5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin 

Relevant articles and documents

Polyether-bridged sexithiophene as a complexation-gated molecular wire for intramolecular photoinduced electron transfer

The porphyrin-sexithiophene-fullerene triad 2, where the two central thiophene units of the sexithiophene spacer are bridged with a crown-ether-like polyether chain, undergoes efficient intramolecular electron transfer from the photoexcited porphyrin moie

A Synthetic Strategy for Cofacial Porphyrin-Based Homo- and Heterobimetallic Complexes

We present a straightforward and generally applicable synthesis route for cofacially linked homo- and heterobimetallic porphyrin complexes. The protocol allows the synthesis of unsymmetrical aryl-based meso-meso as well as β-meso-linked porphyrins. Our method significantly increases the overall yield for the published compound known as o-phenylene-bisporphyrin (OBBP) by a factor of 6.8. Besides the synthesis of 16 novel homobimetallic complexes containing MnIII, FeIII, NiII, CuII, ZnII, and PdII, we achieved the first single-crystal X-ray structure of an unsymmetrical cofacial benzene-linked porphyrin dimer containing both planar-chiral enantiomers of a NiII2 complex. Additionally, this new methodology allows access to heterobimetallic complexes such as the FeIII-NiII containing carbon monoxide dehydrogenase active site analogue. The isolated species were investigated by various techniques, including ion mobility spectrometry, DFT calculations, and UV/Vis spectroscopy. This allowed us to probe the influence of interplane distance on Soret band splitting.

Metal-catalyzed direct heteroarylation of C-H (: Meso) bonds in porphyrins: Facile synthesis and photophysical properties of novel meso -heteroaromatic appended porphyrins

A simple and rapid microwave-assisted synthesis of heteroaromatic appended porphyrins using the Pd/Cu-catalyzed C-C coupling of meso-bromoporphyrins with various five- and six-membered heteroaromatic azoles has been successfully developed. The prepared he