5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Base Information

Chemical Name:5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl
CAS No.:896507-45-2
Molecular Formula:C₆₁H₆₇IO₁₄
Molecular Weight:1151.1
Hs Code.:

Synonyms:5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Suppliers and Price of 5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

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Chemical Property of 5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Chemical Property:

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Safty Information:

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Technology Process of 5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

There total 14 articles about 5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.3%

: 906646-96-6
5-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

: 896507-45-2
5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Guidance literature:: With 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; In tetrahydrofuran; at 0 ℃; for 24h;
DOI:10.1021/ja062171v

Reference yield:

: 17715-69-4
1-Bromo-2,4-dimethoxybenzene

: 896507-45-2
5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Guidance literature:: Multi-step reaction with 9 steps

1.1: n-BuLi / tetrahydrofuran / 1 h / -78 °C

1.2: tetrahydrofuran / 24 h / -78 °C

2.1: Acid hydrolysis

3.1: 88.8 percent / aq. Na₂CO₃ / Pd(PPh₃)4 / tetrahydrofuran / 168000 h / Heating

4.1: 41.6 percent / 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 0 °C

5.1: 71.6 percent / aq. K₂CO₃ / Pd(PPh₃)4 / toluene / 48 h / 80 °C

6.1: 100 percent / 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 0 °C

7.1: 85.1 percent / Net₃ / PdCl₂(PPh₃)2 / dioxane / 80 °C

8.1: 62.9 percent / aq. K₂CO₃ / Pd(PPh₃)4 / toluene / 48 h / 80 °C

9.1: 90.3 percent / 1,3-diiodo-5,5-dimethylhydantoin / tetrahydrofuran / 24 h / 0 °C

With n-butyllithium; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; sodium carbonate; potassium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; toluene;
DOI:10.1021/ja062171v

Reference yield:

: 151-10-0
1,3-Dimethoxybenzene

: 896507-45-2
5-iodo-5''''''-[(S)-2-methylbutyl]-2,4,4',6',4'',6'',4''',6''',4'''',6'''',4''''',6''''',2'''''',4''''''-tetradecamethoxy-1,1':3',1'':3'',1''':3''',1'''':3'''',1''''':3''''',1''''''-septiphenyl

Guidance literature:: Multi-step reaction with 10 steps

1.1: 96 percent / 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 24 h / 0 °C

2.1: n-BuLi / tetrahydrofuran / 1 h / -78 °C

2.2: tetrahydrofuran / 24 h / -78 °C

3.1: Acid hydrolysis

4.1: 88.8 percent / aq. Na₂CO₃ / Pd(PPh₃)4 / tetrahydrofuran / 168000 h / Heating

5.1: 41.6 percent / 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 0 °C

6.1: 71.6 percent / aq. K₂CO₃ / Pd(PPh₃)4 / toluene / 48 h / 80 °C

7.1: 100 percent / 1,3-dibromo-5,5-dimethylhydantoin / tetrahydrofuran / 0 °C

8.1: 85.1 percent / Net₃ / PdCl₂(PPh₃)2 / dioxane / 80 °C

9.1: 62.9 percent / aq. K₂CO₃ / Pd(PPh₃)4 / toluene / 48 h / 80 °C

10.1: 90.3 percent / 1,3-diiodo-5,5-dimethylhydantoin / tetrahydrofuran / 24 h / 0 °C

With n-butyllithium; 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione; sodium carbonate; potassium carbonate; triethylamine; bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; toluene;
DOI:10.1021/ja062171v