amino(triphenyl)phosphonium chloride

Base Information

• Chemical Name: amino(triphenyl)phosphonium chloride
• CAS No.: 15729-44-9
• Molecular Formula: C₁₈H₁₇NP*Cl
• Molecular Weight: 313.766
• Mol file: 15729-44-9.mol

Synonyms:amino(triphenyl)phosphonium chloride

Chemical Property of amino(triphenyl)phosphonium chloride

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

AMINOTRIPHENYLPHOSPHONIUM CHLORIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of amino(triphenyl)phosphonium chloride

There total 8 articles about amino(triphenyl)phosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

triphenylphosphine (603-35-0) → amino(triphenyl)phosphonium chloride (15729-44-9)

Guidance literature:

triphenylphosphine; With hexachloroethane; In tetrahydrofuran; at 25 ℃; Inert atmosphere;

With ammonia; In tetrahydrofuran; at -25 - 25 ℃; Inert atmosphere;

DOI:10.1002/adsc.200800428

Reference yield: 65.0%

(triphenylphosphoranediyl)aminocyclotrithiatriazene (33082-06-3) → amino(triphenyl)phosphonium chloride (15729-44-9)

Guidance literature:

With nickel dichloride; In acetonitrile; at 20 ℃; for 18h;

DOI:10.1139/v02-140

Reference yield: 40.0%

trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) (15318-33-9,16353-77-8,13938-94-8) → Rh(CO)(P(C6H5)3)2Cl3 (16969-79-2,24322-80-3) + imino(triphenyl)phosphorane (2240-47-3) + amino(triphenyl)phosphonium chloride (15729-44-9) + triphenylphosphine sulfide (3878-45-3)

Guidance literature:

With NSCl*C₄H₈O; In not given; soln. of Rh-complex in THF or CH2Cl2 was treated with 1 equiv of soln. of NSCl*THF in THF, stirred for ca. 1 h;

upstream raw materials:

triphenylphosphine

dibromotriphenylphosphorane

(triphenylphosphoranediyl)aminocyclotrithiatriazene

chloroamine

Downstream raw materials:

lithium triphenylphosphonium azayldiide

Triphenylphosphin-N-brom-imin

Br^(1-)*C₂₈H₂₆NP₂⁽¹⁺⁾

Br^(1-)*C₂₄H₂₇N₄P₂⁽¹⁺⁾