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CAS

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33082-06-3

(triphenylphosphoranediyl)aminocyclotrithiatriazene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 33082-06-3 Structure

  • Basic information

    1. Product Name: (triphenylphosphoranediyl)aminocyclotrithiatriazene
    2. Synonyms: (triphenylphosphoranediyl)aminocyclotrithiatriazene
    3. CAS NO:33082-06-3
    4. Molecular Formula:
    5. Molecular Weight: 414.516
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 33082-06-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (triphenylphosphoranediyl)aminocyclotrithiatriazene(CAS DataBase Reference)
    10. NIST Chemistry Reference: (triphenylphosphoranediyl)aminocyclotrithiatriazene(33082-06-3)
    11. EPA Substance Registry System: (triphenylphosphoranediyl)aminocyclotrithiatriazene(33082-06-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 33082-06-3(Hazardous Substances Data)

33082-06-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 33082-06-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,3,0,8 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 33082-06:
(7*3)+(6*3)+(5*0)+(4*8)+(3*2)+(2*0)+(1*6)=83
83 % 10 = 3
So 33082-06-3 is a valid CAS Registry Number.

33082-06-3Relevant articles and documents

Studies on iodination reactions of phosphiniminocyclotrithiazenes

Sivaramakrishna, Akella,Swarnalatha,Sudheendra Rao

, p. 1349 - 1354 (2013)

Iodination reactions of various phosphiniminocyclotrithiazenes [R 3PNS3N3; R = (i) phenyl-, (ii) morpholino-, and (iii) p-chlorophenyl-] have been studied under different experimental conditions. Iodination of Ph3PNS3N3 yields interesting products such as [(Ph3PN)2S3N 3]I3, ((Ph3PN)3S)2I 4, (Ph3PNH2)I3, ((Ph 3PSI2)2I2, and [(Ph 3PN)3SO]2I6 depending on the experimental conditions. All the products have been isolated and characterized by the spectroscopic and analytical techniques. Copyright Taylor & Francis Group, LLC.

INVESTIGATIONS ON THE COOPERATIVE EFFECTS OF PHOSPHINES: A CASE STUDY OF THE REACTIONS OF S4N4, Ph3P AND Ph2PR (R = p-CH3C6H4-(I) AND OC4H8N-(II))

Elias, Anil J.,Thomas, C. J.,Rao, M.N. Sudheendra

, p. 253 - 256 (2007/10/02)

Reactions of tetrasulphur tetranitride and triphenylphosphine in presence of Phosphine (I) or (II) have been studied.In case of p-tolyldiphenylphosphine(I), in addition to the trisulphurtrinitride derivatives (III and VI) and compound (V), mixed phosphine derivatives (VII to IX) are obtained.In case of morpholinodiphenylphosphine(II), the corresponding trisulphurtrinitride derivatives (III and X) and compound (V) are the only cyclic products isolated.New products have been characterized by physical, spectroscopic and analytical data.The two phosphines seem to exert different effects.

The cycloaddition of norbornadiene to (triphenylphosphoranediyl)aminocyclotrithiatriazene; the crystal and molecular structure of Ph3PN-S3N3*C7H8

Liblong, Stephen W.,Oakley, Richard T.,Cordes, A. Wallace,Noble, Mark C.

, p. 2062 - 2067 (2007/10/02)

The reaction of norbornadiene with (triphenylphosphoranediyl)aminocyclotrithiatriazene produces the cycloadduct Ph3PN-S3N3*C7H8.The crystal and molecular structure of this compound has been determined by X-ray crystallography.Crystals of Ph3PN-S3N3*C7H8 are monoclinic, space group P21/c, a=9.757(1), b=15.114(1), c=16.535(2) Angstroem, β=100.73(1) deg, V=2395.7(9) Angstroem3, and Z=4.The structure was solved by direct methods and refined by Furier and full-matrix least-squares procedures to give a final R of 0.040 and Rw of 0.058 for 2620 observed reflections.The structure reveals that the S3N3 ring adds to norbornadiene in an exo fashion via two sulphur atoms.The S3N3 ring adopts a chair conformation with the three ligands occupying axial positions an the same side of the ring.The relative rates of this and other cycloadditions involving SN substrates and olefins are discussed in terms of the energies of the interacting frontier orbitals.The results suggest that HOMO(olefin)-LUMO(SN substrate) interactions control the kinetics of these reactions.

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