5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH

Base Information

• Chemical Name: 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH
• CAS No.: 796055-70-4
• Molecular Formula: C₆₆H₇₈Se
• Molecular Weight: 950.305
• Mol file: 796055-70-4.mol

Synonyms:5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH

Chemical Property of 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH

There total 2 articles about 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeI (1215863-28-7) → 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH (796055-70-4)

Guidance literature:

With DL-dithiothreitol; triethylamine; In chloroform-d1; at 20 ℃; for 0.333333h; Inert atmosphere;

DOI:10.1002/anie.200905796

Reference yield: 86.2%

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl iodide (362011-06-1) → 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH (796055-70-4)

Guidance literature:

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl iodide; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -76 ℃; for 0.5h;

With selenium; In tetrahydrofuran; pentane; at -76 - 20 ℃;

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1021/ja0457009

Reference yield: 99.0%

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeH (796055-70-4) → 5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeI (1215863-28-7)

Guidance literature:

With N-iodo-succinimide; In tetrachloromethane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.200905796

upstream raw materials:

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl iodide

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeI

Downstream raw materials:

C₆₆H₇₇NOSe

5',5'''-bis(2,6-diisopropylphenyl)-2,6,2'''',6''''-tetraisopropyl-m-quinquephenyl-2''-yl-SeI