1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene

Base Information

• Chemical Name: 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene
• CAS No.: 182273-78-5
• Molecular Formula: C₂₆H₂₂FeN₄O₄
• Molecular Weight: 510.332
• Mol file: 182273-78-5.mol

Synonyms:1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene

Chemical Property of 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene

There total 2 articles about 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

1,1'-diacetylferrocene (1273-94-5) + N-sulphinyl-p-nitroaniline (13165-67-8,52866-95-2) → 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene (182273-78-5)

Guidance literature:

With silica-supported Ti imido complex; In toluene; for 4h; Inert atmosphere; Reflux; Schlenk technique;

DOI:10.1016/j.jorganchem.2019.01.018

Reference yield: 10.0%

1,1'-diacetylferrocene (1273-94-5) + 4-nitro-aniline (100-01-6,104810-17-5) → 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene (182273-78-5)

Guidance literature:

aluminum oxide; In toluene; Dean-Stark apparatus; mixt. with MgSO4 was refluxed for 48 h under N2; after filtration through Celite solvent and excess amines were removed, ppt. was recrystd. from CH2Cl2/hexane;

DOI:10.1016/j.molstruc.2009.06.047

Reference yield: 13.0%

lithium tetrachloropalladate + 1,1’-bis[1-(4-nitrophenylimino)ethyl]ferrocene (182273-78-5) + triphenylphosphine (603-35-0) → [Fe(C5H3C(CH3)N(C6H4NO2)PdCl(P(C6H5)3))2] (185226-39-5,185066-01-7) + [Fe(C5H3C(CH3)N(C6H4NO2)PdCl(P(C6H5)3))2] (185226-39-5,185066-01-7)

Guidance literature:

With sodium acetate; In methanol; dichloromethane; stirring the palladate and ferrocenylimine in the presence of anhydrous NaOAc in MeOH/CH2Cl2 at room temp. for ca. 20 h, evapn. (vac.), washing (MeOH), addn. of PPh3 in CH2Cl2, stirring (room temp., 0.5 h); chromy. (SiO2; CH2Cl2), evapn., recrystn. (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1016/0277-5387(96)00101-5

upstream raw materials:

1,1'-diacetylferrocene

4-nitro-aniline

N-sulphinyl-p-nitroaniline

Downstream raw materials:

[Fe(C₅H₃C(CH₃)N(C₆H₄NO₂)PdCl(P(C₆H₅)3))2]

[Fe(C₅H₃C(CH₃)N(C₆H₄NO₂)PdCl(P(C₆H₅)3))2]

[Fe((η5-C5H4)C(CH3)NC6H4-4-NO2)2](1+)