2-(5-Nitro-alpha-iminofurfuryl)hydrazine

Base Information

• Chemical Name: 2-(5-Nitro-alpha-iminofurfuryl)hydrazine
• CAS No.: 13295-76-6
• Molecular Formula: C5H6 N4 O3
• Molecular Weight: 170.15
• Mol file: 13295-76-6.mol

Synonyms:2-(5-Nitro-alpha-iminofurfuryl)hydrazine;5-Nitro-2-furohydrazide imide;13295-76-6;Hydrazine, 2-(5-nitro-alpha-iminofurfuryl)-;2-Furancarboximidic acid, 5-nitro-, hydrazide;N'-amino-5-nitrofuran-2-carboximidamide;LS-76923

Chemical Property of 2-(5-Nitro-alpha-iminofurfuryl)hydrazine

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.8300 (estimate)
• Boiling Point: 370°Cat760mmHg
• Flash Point: 177.6°C
• PSA: 120.86000
• Density: 1.79g/cm³
• LogP: 1.69060
• XLogP3: 0.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 1
• Exact Mass: 170.04399007
• Heavy Atom Count: 12
• Complexity: 211

Purity/Quality:

99% ^*data from raw suppliers

5-NITRO-2-FUROHYDRAZIDEIMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=C(OC(=C1)[N+](=O)[O-])C(=NN)N
• Isomeric SMILES: C1=C(OC(=C1)[N+](=O)[O-])/C(=N\N)/N

Technology Process of 2-(5-Nitro-alpha-iminofurfuryl)hydrazine

There total 4 articles about 2-(5-Nitro-alpha-iminofurfuryl)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

5-nitrofuran-2-carbonitrile (59-82-5) → 5-nitro-2-furancarbohydrazone acid amide (13295-76-6)

Guidance literature:

With hydrazine hydrate; In ethanol;

DOI:10.1007/BF00519931

Reference yield: 71.5%

5-nitrofuran-2-carbonitrile (59-82-5) → amidrazone of 5-nitro-2-furancarboxylic acid (13295-76-6)

Guidance literature:

With hydrazine hydrate; In ethanol; Ambient temperature;

DOI:10.1007/BF01184877

Reference yield:

5-nitro-furfural-(E)-oxime (7197-93-5) → amidrazone of 5-nitro-2-furancarboxylic acid (13295-76-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 80 percent / SOCl₂ / Ambient temperature

2: 71.5 percent / NH₂NH₂*H₂O / ethanol / Ambient temperature

With thionyl chloride; hydrazine hydrate; In ethanol;

DOI:10.1007/BF01184877

upstream raw materials:

5-nitrofuran-2-carbonitrile

5-nitrofurane-2-carboxaldehyde

5-nitro-furfural-(E)-oxime

Downstream raw materials:

1-benzylidene amidrazone of 5-nitro-2-furancarboxylic acid

C₁₃H₁₂N₄O₄

C₁₄H₁₅N₅O₃

1-Propionyl-3-(5-nitro-2-furyl)-5-ethyl-1,2,4-triazol

Refernces

• 1、 Pavlov, P. A.,Kul'nevich, V. G.. "SYNTHESIS OF 5-SUBSTITUTED CYANOFURANS AND THEIR REACTION WITH HYDRAZINE". . p. 140 - 145. Retrieved 2007/10/02.