(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

Base Information

Chemical Name:(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate
CAS No.:941715-55-5
Molecular Formula:C₄₀H₆₅NO₄Si
Molecular Weight:652.046
Hs Code.:

Synonyms:(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

Chemical Property:

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Technology Process of (2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

There total 5 articles about (2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₄₀H₆₇NO₄Si

: 941715-55-5
(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

Guidance literature:: With pyridine-SO₃ complex; triethylamine; In dichloromethane; dimethyl sulfoxide; at 20 ℃;
DOI:10.1002/ejoc.200601009

Reference yield:

: 941715-39-5
(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-hepten-3-ol

: 941715-55-5
(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

Guidance literature:: Multi-step reaction with 5 steps

1: 87 percent / DMAP / CH₂Cl₂ / 1.5 h

2: NMO / OsO₄ / acetone; H₂O; toluene / 8 h / 20 °C

3: 1.26 g / NaIO₄/SiO₂ / CH₂Cl₂ / 1 h / 0 °C

4: diethyl ether / -78 °C

5: 993 mg / SO₃*Py; triethylamine / dimethylsulfoxide; CH₂Cl₂ / 20 °C

With dmap; sodium periodate; N-methyl-2-indolinone; pyridine-SO₃ complex; silica gel; triethylamine; osmium(VIII) oxide; In diethyl ether; dichloromethane; water; dimethyl sulfoxide; acetone; toluene;
DOI:10.1002/ejoc.200601009

Reference yield:

: 941715-45-3
(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-hepten-3-yl acetate

: 941715-55-5
(2R,3R)-1-(tert-butyldimethylsilyloxy)-2-(dibenzylamino)-6-oxooctadec-3-yl acetate

Guidance literature:: Multi-step reaction with 4 steps

1: NMO / OsO₄ / acetone; H₂O; toluene / 8 h / 20 °C

2: 1.26 g / NaIO₄/SiO₂ / CH₂Cl₂ / 1 h / 0 °C

3: diethyl ether / -78 °C

4: 993 mg / SO₃*Py; triethylamine / dimethylsulfoxide; CH₂Cl₂ / 20 °C

With sodium periodate; N-methyl-2-indolinone; pyridine-SO₃ complex; silica gel; triethylamine; osmium(VIII) oxide; In diethyl ether; dichloromethane; water; dimethyl sulfoxide; acetone; toluene;
DOI:10.1002/ejoc.200601009