titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)

Base Information

Chemical Name:titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)
CAS No.:12113-37-0
Molecular Formula:C18H22 Cl2 Ti
Molecular Weight:357.1403
Hs Code.:
Mol file:12113-37-0.mol

Synonyms:Titanium,dichlorobis(4,5,6,7-tetrahydro-p-indenyl)- (8CI); Bis(h5-(4,5,6,7-tetrahydro-1H-indenyl))titanium dichloride; Dichlorobis(p-tetrahydroindenyl)titanium

Suppliers and Price of titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)

Chemical Property:

Vapor Pressure:0.776mmHg at 25°C
Boiling Point:189.7°C at 760 mmHg
Flash Point:45.6°C

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2)

There total 2 articles about titanium(4+) chloride 4,5,6,7-tetrahydroinden-3a-ide (1:2:2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: lithium bicyclo [4:3:0] non-6,8-dienyl

: 7550-45-0
titanium tetrachloride

: 12113-37-0
bis[η5-(4,5,6,7-tetrahydro-1H-indenyl)]titanium dichloride

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; N2-atmosphere; slow addn. of excess of Li-salt to TiCl4 at -78°C,stirring (room temp., overnight); evapn. (reduced pressure), extn. into MePh, filtration off of LiCl, concn., crystn. (-20°C, overnight), filtration, washing (MePh, 0°C), drying (vac.); elem. anal.;
DOI:10.1016/S0022-328X(98)01042-0

Reference yield:

: 24279-06-9
bicyclo<4.3.0>nona-1(6),7-diene

: 7550-45-0
titanium tetrachloride

: 12113-37-0
bis[η5-(4,5,6,7-tetrahydro-1H-indenyl)]titanium dichloride

Guidance literature:: With n-butyllithium; chloro-trimethyl-silane; ammonium chloride; In tetrahydrofuran; dichloromethane; Petroleum ether; Ar; nBuLi, diene, petroleum ether, -10°C; stirring, room temp.; ppt. dissolved in THF; Me3SiCl in THF added; stirring, room temp., 6 h; aq. NH4Cl added, 0°C; extd. with Et2O; evapn.; dissolved in CH2Cl2; TiCl4/CH2Cl2 added, stirring; solvent removed under vac., residue washed with petroleum ether, dried; elem. anal.;
DOI:10.1039/b315482c

Reference yield: 75.0%

: 12113-37-0
bis[η5-(4,5,6,7-tetrahydro-1H-indenyl)]titanium dichloride

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

: 205586-35-2
(tetrahydroindenyl)2Ti(η(2)-phenyl(trimethylsilyl)acetylene)

Guidance literature:: With Mg; In tetrahydrofuran; byproducts: MgCl2; Ar atmosphere, addn. of Mg turnings and alkyne to soln. of Ti complex, heating to 50°C, stirring (room temp., 3 h); removement of solvent, dissolution (n-hexane), filtration, crystn. (-30°C); elem. anal.;
DOI:10.1002/(SICI)1099-0682(199803)1998:3<419::AID-EJIC419>3.0.CO;2-D