5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

Base Information

Chemical Name:5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one
CAS No.:112698-59-6
Molecular Formula:C₁₈H₁₈O₃S
Molecular Weight:314.405
Hs Code.:

5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0<sup>2,6</sup>>deca-4,8-dien-3-one

Synonyms:5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

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Chemical Property of 5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

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Technology Process of 5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

There total 6 articles about 5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 112698-71-2
5-ethoxy-4-(p-tolylsulphonyl)methyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

: 930-69-8
sodium thiophenolate

: 112698-59-6
5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

Guidance literature:: In methanol; 1.) reflux, 4 h; 2.) room temp., overnight;
DOI:10.1016/S0040-4020(01)89179-1

Reference yield:

: 368-39-8
triethyloxonium fluoroborate

: 127588-18-5
5-hydroxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

: 622-38-8
Ethyl phenyl sulfide

: 112698-59-6
5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

Guidance literature:: With triethylamine; In dichloromethane; Yield given;
DOI:10.1016/S0040-4020(01)89179-1

Reference yield:

: 62926-69-6,69608-99-7
5-hydroxy-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

: 112698-59-6
5-ethoxy-4-phenylthiomethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) glacial acetic acid / 1.) DMF, 70 deg C, 2h; 2.) 0 deg C, 3 h; room temp. overnight

2: 90 percent / 1.) triethylamine / CH₂Cl₂ / 3 h / Ambient temperature

3: 43 percent / methanol / 1.) reflux, 4 h; 2.) room temp., overnight

With acetic acid; triethylamine; In methanol; dichloromethane;
DOI:10.1016/S0040-4020(01)89179-1