7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

Base Information

Chemical Name:7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester
CAS No.:791610-18-9
Molecular Formula:C₃₂H₄₀O₄Si
Molecular Weight:516.753
Hs Code.:

7-(<i>tert</i>-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

Synonyms:7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

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Chemical Property of 7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

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Technology Process of 7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

There total 1 articles about 7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.8%

: 74-88-4
methyl iodide

: 7-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptanoic acid benzyl ester

: 791610-18-9
7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

Guidance literature:: 7-(tert-butyl-diphenyl-silanyloxy)-3-oxo-heptanoic acid benzyl ester; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 12h;

methyl iodide; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1021/ol048578r

Reference yield:

: 791610-18-9
7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

: 7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid

Guidance literature:: With hydrogen; palladium on activated charcoal; In diethyl ether; at 0 ℃; for 3h;
DOI:10.1021/ol048578r

Reference yield:

: 791610-18-9
7-(tert-butyl-diphenyl-silanyloxy)-2,2-dimethyl-3-oxo-heptanoic acid benzyl ester

: 791610-19-0
8-(tert-butyl-diphenyl-silanyloxy)-1-diazo-3,3-dimethyl-octane-2,4-dione

Guidance literature:: Multi-step reaction with 2 steps

1.1: H₂ / Pd/C / diethyl ether / 3 h / 0 °C

2.1: ClCOOMe; Et₃N / diethyl ether / 1.5 h / 0 °C

2.2: 1.3136 g / diethyl ether / 0 - 20 °C

With hydrogen; triethylamine; methyl chloroformate; palladium on activated charcoal; In diethyl ether;
DOI:10.1021/ol048578r