(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

Base Information

Chemical Name:(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester
CAS No.:204325-23-5
Molecular Formula:C₃₇H₅₀O₅Si
Molecular Weight:602.886
Hs Code.:

Synonyms:(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

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Chemical Property of (2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

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Technology Process of (2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

There total 7 articles about (2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 204325-30-4
(Z)-6-Cyclopropyl-9-hydroxy-2-methylene-non-5-enoic acid methyl ester

: 6-(tert-Butyl-diphenyl-silanyloxy)-2-(dimethoxy-phosphoryl)-hexanoic acid methyl ester

: 204325-23-5
(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

Guidance literature:: With sodium hydride; at 0 ℃;
DOI:10.1039/a707320h

Reference yield:

: 1121-37-5
dicyclopropyl ketone

: 204325-23-5
(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) MeMgBr, Mg / 1.) THF, -30 deg C; 70 deg C

2: 97 percent / imidazole

3: 64 percent / NIS, PPh₃ / CH₂Cl₂ / -30 °C

4: 73 percent / NaH / dimethylsulfoxide

5: 85 percent / NaH

6: TBAF

7: 87 percent / NaH / 0 °C

With 1H-imidazole; N-iodo-succinimide; methylmagnesium bromide; tetrabutyl ammonium fluoride; sodium hydride; magnesium; triphenylphosphine; In dichloromethane; dimethyl sulfoxide;
DOI:10.1039/a707320h

Reference yield:

: 204325-20-2
1,1-Dicyclopropyl-butane-1,4-diol

: 204325-23-5
(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / imidazole

2: 64 percent / NIS, PPh₃ / CH₂Cl₂ / -30 °C

3: 73 percent / NaH / dimethylsulfoxide

4: 85 percent / NaH

5: TBAF

6: 87 percent / NaH / 0 °C

With 1H-imidazole; N-iodo-succinimide; tetrabutyl ammonium fluoride; sodium hydride; triphenylphosphine; In dichloromethane; dimethyl sulfoxide;
DOI:10.1039/a707320h