4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol

Base Information

• Chemical Name: 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol
• CAS No.: 204325-28-0
• Molecular Formula: C₂₆H₃₆O₂Si
• Molecular Weight: 408.656
• Mol file: 204325-28-0.mol

Synonyms:4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol

Chemical Property of 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol

There total 2 articles about 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tert-butylchlorodiphenylsilane (58479-61-1) + 1,1-Dicyclopropyl-butane-1,4-diol (204325-20-2) → 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol (204325-28-0)

Guidance literature:

With 1H-imidazole;

DOI:10.1039/a707320h

Reference yield:

dicyclopropyl ketone (1121-37-5) → 4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol (204325-28-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) MeMgBr, Mg / 1.) THF, -30 deg C; 70 deg C

2: 97 percent / imidazole

With 1H-imidazole; methylmagnesium bromide; magnesium;

DOI:10.1039/a707320h

Reference yield: 64.0%

4-(tert-Butyl-diphenyl-silanyloxy)-1,1-dicyclopropyl-butan-1-ol (204325-28-0) → tert-Butyl-((Z)-4-cyclopropyl-7-iodo-hept-4-enyloxy)-diphenyl-silane (204325-21-3)

Guidance literature:

With N-iodo-succinimide; triphenylphosphine; In dichloromethane; at -30 ℃;

DOI:10.1039/a707320h

upstream raw materials:

tert-butylchlorodiphenylsilane

1,1-Dicyclopropyl-butane-1,4-diol

dicyclopropyl ketone

Downstream raw materials:

tert-Butyl-((Z)-4-cyclopropyl-7-iodo-hept-4-enyloxy)-diphenyl-silane

(Z)-9-(tert-Butyl-diphenyl-silanyloxy)-6-cyclopropyl-2-methylene-non-5-enoic acid methyl ester

(2Z,6Z)-6-Cyclopropyl-10-methylene-2-(3-phenylselanylcarbonyl-propyl)-undeca-2,6-dienedioic acid dimethyl ester

(2Z,6Z)-2-[4-(tert-Butyl-diphenyl-silanyloxy)-butyl]-6-cyclopropyl-10-methylene-undeca-2,6-dienedioic acid dimethyl ester