Technology Process of C27H30O5
There total 9 articles about C27H30O5 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: titanium(IV) isopropylate; (S)-[1,1']-binaphthalenyl-2,2'-diol / dichloromethane / 0.17 h / 20 °C
1.2: 24 h / -78 °C
2.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 15 h / 0 - 20 °C
3.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 24 h / 20 °C
4.1: sodium periodate / tetrahydrofuran; water
5.1: L-proline / chloroform / 4 h / 0 °C
5.2: 1.5 h / 20 °C
6.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 12 h / 0 - 20 °C
7.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 24 h / 20 °C
8.1: sodium periodate / tetrahydrofuran; water
With
titanium(IV) isopropylate; sodium periodate; osmium(VIII) oxide; (S)-[1,1']-binaphthalenyl-2,2'-diol; tetra-(n-butyl)ammonium iodide; sodium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; L-proline;
In
tetrahydrofuran; dichloromethane; chloroform; water; acetone;
1.2: Keck allylation;
DOI:10.1016/j.tetlet.2011.09.105
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 24 h / 20 °C
2.1: sodium periodate / tetrahydrofuran; water
3.1: L-proline / chloroform / 4 h / 0 °C
3.2: 1.5 h / 20 °C
4.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 12 h / 0 - 20 °C
5.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 24 h / 20 °C
6.1: sodium periodate / tetrahydrofuran; water
With
sodium periodate; osmium(VIII) oxide; tetra-(n-butyl)ammonium iodide; sodium hydride; 4-methylmorpholine N-oxide; L-proline;
In
tetrahydrofuran; chloroform; water; acetone;
DOI:10.1016/j.tetlet.2011.09.105
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: sodium periodate / tetrahydrofuran; water
2.1: L-proline / chloroform / 4 h / 0 °C
2.2: 1.5 h / 20 °C
3.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 12 h / 0 - 20 °C
4.1: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone / 24 h / 20 °C
5.1: sodium periodate / tetrahydrofuran; water
With
sodium periodate; osmium(VIII) oxide; tetra-(n-butyl)ammonium iodide; sodium hydride; 4-methylmorpholine N-oxide; L-proline;
In
tetrahydrofuran; chloroform; water; acetone;
DOI:10.1016/j.tetlet.2011.09.105