[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

Base Information

Chemical Name:[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]
CAS No.:357423-94-0
Molecular Formula:C₃₇H₃₆N₂O₂PRu*F₆P
Molecular Weight:817.713
Hs Code.:

Synonyms:[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

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Chemical Property of [(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

Chemical Property:

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Technology Process of [(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

There total 1 articles about [(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 181649-59-2,209118-24-1
[tris(acetonitrile)(η(5)-1-ethoxycarbonyl-2-methyl-4-phenylcyclopentadienyl)ruthenium] hexafluorophosphate

: 603-35-0
triphenylphosphine

: 357423-94-0
[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

Guidance literature:: In dichloromethane; (Ar); addn. of PPh3 to soln. of ((C5H2(Me)(Ph)(COOEt))Ru(MeCN)3)PF6 in CH2Cl2 at -78°C; stirring for 1 h; removal of solvent under reduced pressure, washing with ether, drying invac., elem. anal.;
DOI:10.1021/om0102246

Reference yield: 83.0%

: 357423-94-0
[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

: 78-79-5,9003-31-0
isoprene

: 700377-46-4,700842-51-9
[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(isoprene)][PF6]

Guidance literature:: In dichloromethane; (Ar); diene (10 equiv.) was added to soln. of Ru complex in CH2Cl2; mixt. was refluxed for 12 h; solvent evapd.; chromd. (alumina, CH2Cl2); solvent evapd.; washed (ether); dried (vac.); elem. anal.;
DOI:10.1021/om049917n

Reference yield:

: 3117-65-5
2-(methyliminomethyl)phenol

: 357423-94-0
[(η5-cyclopentadienyl-2-Me-4-Ph-1-CO2CH2CH3)(PPh3)ruthenium(acetonitrile)2][PF6]

: [Ru(OC₆H₄CHNCH₃)(P(C₆H₅)3)((CH₃)(C₆H₅)C₅H₂COOCH₂CH₃)]

: [Ru(OC₆H₄CHNCH₃)(P(C₆H₅)3)((CH₃)(C₆H₅)C₅H₂COOCH₂CH₃)]

Guidance literature:: With NaH; In tetrahydrofuran; (Ar); washing of NaH in dry hexane, suspending in THF, addn. of C6H4(CHNCH3)OH, stirring at room temp. for 15 min; filtration, pouring of filtrate into suspn. of (Ru(MeCN)2(PPh3)((CH3)(C6H5)C5H2COOC2H5))PF6 in THF; stirring at room temp. for 1 h; removal of solvent under reduced pressure, dissolving in CH2Cl2, addn. of hexane, filtration, concn. under reduced pressure, recrystn. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om0102246