[CpFe(CO)2C₆H₄-4-F]

Base Information

Chemical Name:[CpFe(CO)2C₆H₄-4-F]
CAS No.:183867-88-1
Molecular Formula:C₁₃H₉BrFeO₂
Molecular Weight:332.964
Hs Code.:

[CpFe(CO)2C<sub>6</sub>H<sub>4</sub>-4-F]

Synonyms:[CpFe(CO)2C₆H₄-4-F]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [CpFe(CO)2C₆H₄-4-F]

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Technology Process of [CpFe(CO)2C₆H₄-4-F]

There total 3 articles about [CpFe(CO)2C₆H₄-4-F] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 4-BrC₆H₄ZnI*LiCl

: 183867-88-1
[CpFe(CO)2C₆H₄-4-F]

Guidance literature:: With palladium diacetate; In tetrahydrofuran; under Ar atm. Fe complex, Pd(OAc)2, diamine, and arylzinc iodide -LiCl complex in THF were stirred at 0°C for 15 min; aq. NH4Cl was added, product was extd. with EtOAc, passed through Na2SO4/Florisil pad and chromd. on silica (CS2);
DOI:10.1021/om800916r

Reference yield: 51.0%

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 589-87-7
1,4-bromoiodobenzene

: 183867-88-1
[CpFe(CO)2C₆H₄-4-F]

Guidance literature:: With palladium diacetate; In tetrahydrofuran; IC6H4Br reacted with (CH3)2CHMgCl*LiCl in THF at -20°C for 30 min; reacted with Fe complex, Pd salt and C6H10(N(CH3)2)2 in THF at -20°C for 1 h;
DOI:10.1021/om800560m

Reference yield:

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 183867-88-1
[CpFe(CO)2C₆H₄-4-F]

Guidance literature:: In not given; treatment of iron compd. with arylmetal deriv. in presence of palladium compd.; Yasuda S., Yorimitsu H., Oshima K., Organometallics 2008, 27, 4025-4027; Asada Y., Yasuda S., Yorimitsu H., Oshima K., Organometallics 2008, 27, 6050-6052;
DOI:10.1021/om1001952