diphenylbismuth(III) benzenesulfonate

Base Information

Chemical Name:diphenylbismuth(III) benzenesulfonate
CAS No.:108858-13-5
Molecular Formula:C₁₈H₁₅BiO₃S
Molecular Weight:520.362
Hs Code.:

Synonyms:diphenylbismuth(III) benzenesulfonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of diphenylbismuth(III) benzenesulfonate

Chemical Property:

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Technology Process of diphenylbismuth(III) benzenesulfonate

There total 2 articles about diphenylbismuth(III) benzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 603-33-8
triphenylbismuthane

: 98-11-3
benzenesulfonic acid

: 108858-13-5
diphenylbismuth(III) benzenesulfonate

Guidance literature:: In diethyl ether; mixing soln. of (C6H5)3Bi in ether and soln. of benzenesulfonic acid inether; stirring at room temp. for 15 min, pptn.; filtration; washing with ether; drying at room temp.; elem. anal.;
DOI:10.1016/S0020-1693(00)86855-3

Reference yield: 52.0%

: 7446-11-9
sulfur trioxide

: 603-33-8
triphenylbismuthane

: 108858-13-5
diphenylbismuth(III) benzenesulfonate

Guidance literature:: In 1,2-dichloro-ethane; byproducts: BiO(O3SC6H5); bubbling SO3 through soln. of triphenylbismuth in 1,2-dichloroethane for 2h at -10°C; pptn., filtration; extractn. with dry ethanol (residue containing some BiO(O3SPh)); pptn. on addn. of petroleum ether (40°C); further product on evapn. of filtrate; elem. anal.;
DOI:10.1016/S0020-1693(00)86855-3

Reference yield:

: 108858-13-5
diphenylbismuth(III) benzenesulfonate

: 603-33-8
triphenylbismuthane

: 515-42-4
sodium phenylsulfonate

Guidance literature:: In water; boiling with H2O for 2h;; extn. with ether; identification of (C6H5)3Bi by TLC; filtration of extract, neutralization with NaOH; detn. of NaO3SPh by IR;
DOI:10.1016/S0020-1693(00)86855-3