Triphenylbismuth

Base Information

Chemical Name:Triphenylbismuth
CAS No.:603-33-8
Molecular Formula:C18H15Bi
Molecular Weight:440.298
Hs Code.:29319090
European Community (EC) Number:210-033-4
NSC Number:465
UNII:R18732F41W
DSSTox Substance ID:DTXSID6042498
Wikidata:Q4463253
Mol file:603-33-8.mol

Synonyms:Ph3Bi;triphenyl bismuth;triphenyl bismuthine;triphenylbismuth

Suppliers and Price of Triphenylbismuth

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Triphenylbismuth
2.5g
$ 85.00

Strem Chemicals
Triphenylbismuth, 99%
10g
$ 59.00

Strem Chemicals
Triphenylbismuth, 99%
50g
$ 236.00

Sigma-Aldrich
Triphenylbismuth 98% (99.9% trace metals basis)
1g
$ 65.50

Matrix Scientific
Triphenylbismuthine 95+%
10g
$ 42.00

Matrix Scientific
Triphenylbismuthine 95+%
5g
$ 30.00

Crysdot
Triphenylbismuthine 97%
500g
$ 642.00

Alfa Aesar
Triphenylbismuth 99+%
25g
$ 98.90

Alfa Aesar
Triphenylbismuth 99+%
5g
$ 29.70

Alfa Aesar
Triphenylbismuth 99+%
100g
$ 288.00

Total 130 raw suppliers

Chemical Property of Triphenylbismuth

Chemical Property:

Appearance/Colour:white to off-white crystalline powder
Melting Point:78-80 °C
Refractive Index:1.7040
Boiling Point:310 °C
Flash Point:242 °C/14mm
PSA：0.00000
Density:1.585 g/cm³
LogP:4.46040
Storage Temp.:Inert atmosphere,Room Temperature
Sensitive.:Moisture Sensitive
Solubility.:Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
Water Solubility.:insoluble
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:440.09777
Heavy Atom Count:19
Complexity:202

Purity/Quality:

99% ^*data from raw suppliers

Triphenylbismuth ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22
Safety Statements: 24/25-36/37

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:Metals -> Metals, Organic Compounds
Canonical SMILES:C1=CC=C(C=C1)[Bi](C2=CC=CC=C2)C3=CC=CC=C3
Uses Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

Technology Process of Triphenylbismuth

There total 393 articles about Triphenylbismuth which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 38222-83-2
2,6-di-tert-butyl-4-methylpyridine

: 278172-59-1
methyltriphenylbismuthonium tetrafluoroborate

: 100-51-6,185532-71-2
benzyl alcohol

: 538-86-3
benzyl methyl ether

: 160142-36-9
2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

: 603-33-8
triphenylbismuthane

Guidance literature:: In chloroform-d1; alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR; Kinetics;
DOI:10.1021/om000095d

Reference yield: 100.0%

: 38222-83-2
2,6-di-tert-butyl-4-methylpyridine

: 278172-59-1
methyltriphenylbismuthonium tetrafluoroborate

: 67-63-0,8013-70-5
isopropyl alcohol

: 598-53-8
isopropyl methyl ether

: 160142-36-9
2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

: 603-33-8
triphenylbismuthane

Guidance literature:: In chloroform-d1; alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;
DOI:10.1021/om000095d