trans-propene-d1

Base Information

• Chemical Name: trans-propene-d1
• CAS No.: 1117-91-5
• Molecular Formula: C₃H₆
• Molecular Weight: 43.0727
• Mol file: 1117-91-5.mol

Synonyms:trans-propene-d1

Chemical Property of trans-propene-d1

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of trans-propene-d1

There total 23 articles about trans-propene-d1 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → (Z)-propene-1-d1 (1117-90-4,1560-60-7) + trans-propene-d1 (1117-91-5,1560-60-7) + 3-deuteriopropene (1117-89-1) + propene-2-d1 (1184-59-4)

Guidance literature:

With deuterium; palladium; at -63.1 ℃; Product distribution; Mechanism; also other catalysts ( Ni, Pt, Ni-Cu, Pd-Cu, Pt-Cu, Cu) and reaction conditions (180 - 263 K);

DOI:10.1039/c39870000363

Reference yield:

(Z)-propene-1-d1 (1117-90-4,1560-60-7) → (Z)-1,2-Dideuterioethylen (2813-62-9) + (Z)-2-Butene (590-18-1) + trans-2-Butene (624-64-6) + (E)-ethene-1,2-d2 (1517-53-9) + trans-propene-d1 (1117-91-5,1560-60-7)

Guidance literature:

tetramethylstannane; titanium(IV) oxide; molybdenum(VI) oxide; Ambient temperature; ratio of products to ethylene;

DOI:10.1021/ja00242a028

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → (Z)-propene-1-d1 (1117-90-4,1560-60-7) + trans-propene-d1 (1117-91-5,1560-60-7) + propane (74-98-6) + 3-deuteriopropene (1117-89-1) + propene-2-d1 (1184-59-4)

Guidance literature:

With hydrogen; deuterium; aluminum oxide; zirconium(IV) oxide; at 149.9 ℃; Product distribution; Mechanism; Thermodynamic data; var. concentration of ZrO₂ on var. supports; var. temp.; also with C₃D₆; E_a;

DOI:10.1006/jcat.1995.1172

upstream raw materials:

trans-2-propenyl bromide

methylacetylene-d1

propene

hexadeuteriopropene

Downstream raw materials:

trans-1-deuteriopropylene oxide

methyloxirane

Refernces

• 1、 Kukral, Jürgen,Lehmus, Petri,Klinga, Martti,Leskel?, Markku,Rieger, Bernhard. "Oxygen-containing, asymmetric "dual-side" zirconocenes: Investigations on a reversible chain transfer to aluminum". . p. 1349 - 1356. Retrieved 2007/10/03.
• 2、 Naito, Shuichi,Tanimoto, Mitsutoshi. "Novel Support Effects on the Mechanism of Propene-Deuterium Addition and Exchange Reactions over Dispersed ZrO2". . p. 306 - 313. Retrieved 2007/10/03.