rac-2-[(diphenylphosphino)methyl]bromoferrocene

Base Information

Chemical Name:rac-2-[(diphenylphosphino)methyl]bromoferrocene
CAS No.:867061-28-7
Molecular Formula:C₂₃H₂₀BrFeP
Molecular Weight:463.137
Hs Code.:

Synonyms:rac-2-[(diphenylphosphino)methyl]bromoferrocene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of rac-2-[(diphenylphosphino)methyl]bromoferrocene

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Technology Process of rac-2-[(diphenylphosphino)methyl]bromoferrocene

There total 1 articles about rac-2-[(diphenylphosphino)methyl]bromoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 146387-26-0,32824-44-5,12109-08-9
rac-2-(hydroxymethyl)bromoferrocene

: 829-85-6
diphenylphosphane

: 867061-28-7
rac-2-[(diphenylphosphino)methyl]bromoferrocene

Guidance literature:: With chlorotrimethylsilane; NaI; In acetonitrile; byproducts: NaCl; under Ar atm.; neat chlorotrimethylsilane was introduced at room temp. to mixt. of rac-2-(hydroxymethyl)bromoferrocene, NaI, dry MeCN with stirring; stirred for 5 min; HPPh2 added; mixt. stirred for 24 h; mixt. quenched (satd. aq. NaCl); diluted (Et2O); org. layer sepd.; washed (satd. aq. NaCl); dried (MgSO4); pre-adsorbed on silica gel; transferred onto chromatographic column; eluted (hexane-Et2O); yellow band collected; evapd.; solidified at 4°C;
DOI:10.1016/j.jorganchem.2005.06.035

Reference yield: 73.0%

: 867061-28-7
rac-2-[(diphenylphosphino)methyl]bromoferrocene

: 124-38-9,18923-20-1
carbon dioxide

: hydrogen cation

: ((diphenylphosphino)methyl)ferrocene

: 867061-27-6
rac-2-[(diphenylphosphanyl)methyl]ferrocenecarboxylic acid

Guidance literature:: With butyl lithium; In tetrahydrofuran; hexane; under Ar atm.; soln. of rac-2-((diphenylphosphino)methyl)bromoferrocene in THF cooled to -78°C (EtOH/CO2); treated with BuLi in hexane; stirred for 1 h at -78°C; soln. was poured onto large excess of solid CO2; allowed to stand at room ...; mixt. diluted (CH2Cl2); washed (satd. aq. NaCl); org. phase dried (MgSO4); evapd. (vac.); residue purified by chromy. on silica gel (CH2Cl2/MeOHas eluent (10:1)); ((diphenylphosphino)methyl)ferrocene eluted first; s econd band collected; evapd.; elem...;
DOI:10.1016/j.jorganchem.2005.06.035