[Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2]

Base Information

• Chemical Name: [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2]
• CAS No.: 1256778-89-8
• Molecular Formula: C₅₈H₆₅N₇O₄RuS₂
• Molecular Weight: 1089.4

Synonyms:[Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2]

Chemical Property of [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2]

Chemical Property:

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Technology Process of [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2]

There total 4 articles about [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)_2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) + N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine + ammonium thiocyanate (1147550-11-5) → [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)2] (1256778-89-8)

Guidance literature:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine; In N,N-dimethyl-formamide; at 70 ℃; for 4h; Darkness;

2,2'-Bipyridine-4,4'-dicarboxylic acid; In N,N-dimethyl-formamide; at 160 ℃; for 4h;

ammonium thiocyanate; In N,N-dimethyl-formamide; at 140 ℃; for 4h;

DOI:10.1016/j.ica.2012.09.017

Reference yield:

4-hexylbenzaldehyde (49763-69-1) → [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)2] (1256778-89-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium tert-butylate / tetrahydrofuran / 1 h

2.1: 1,3-bis-(diphenylphosphino)propane; dipalladiumtris(benzylideneacetone); sodium t-butanolate / toluene / 13 h / 80 °C / Schlenk technique; Inert atmosphere

3.1: N,N-dimethyl-formamide / 4 h / 70 °C / Darkness

3.2: 4 h / 160 °C

3.3: 4 h / 140 °C

With dipalladiumtris(benzylideneacetone); 1,3-bis-(diphenylphosphino)propane; potassium tert-butylate; sodium t-butanolate; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; 1.1: |Horner-Wadsworth-Emmons Olefination / 2.1: |Ullmann Condensation;

DOI:10.1016/j.ica.2012.09.017

Reference yield:

diethyl(2-bromopyridin-4-yl)methylphosphonate (1256724-90-9) → [Ru (4,4′-dicarboxy-2,2′-bipyridine) (N-hexyl-4,4′-di(4-hexylstyryl)-2,2′-dipyridylamine) (NCS)2] (1256778-89-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium tert-butylate / tetrahydrofuran / 1 h

2.1: 1,3-bis-(diphenylphosphino)propane; dipalladiumtris(benzylideneacetone); sodium t-butanolate / toluene / 13 h / 80 °C / Schlenk technique; Inert atmosphere

3.1: N,N-dimethyl-formamide / 4 h / 70 °C / Darkness

3.2: 4 h / 160 °C

3.3: 4 h / 140 °C

With dipalladiumtris(benzylideneacetone); 1,3-bis-(diphenylphosphino)propane; potassium tert-butylate; sodium t-butanolate; In tetrahydrofuran; N,N-dimethyl-formamide; toluene; 1.1: |Horner-Wadsworth-Emmons Olefination / 2.1: |Ullmann Condensation;

DOI:10.1016/j.ica.2012.09.017

upstream raw materials:

4-hexylbenzaldehyde

diethyl(2-bromopyridin-4-yl)methylphosphonate

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

2,2'-Bipyridine-4,4'-dicarboxylic acid

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