C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

Base Information

Chemical Name:C₂₇H₃₆SiO₂C₂H₄SiC₃H₈
CAS No.:503000-40-6
Molecular Formula:C₃₂H₄₈O₂Si₂
Molecular Weight:520.903
Hs Code.:

C<sub>27</sub>H<sub>36</sub>SiO<sub>2</sub>C<sub>2</sub>H<sub>4</sub>SiC<sub>3</sub>H<sub>8</sub>

Synonyms:C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

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Chemical Property of C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

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Technology Process of C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

There total 14 articles about C₂₇H₃₆SiO₂C₂H₄SiC₃H₈ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 503000-27-9
(3S)-9-tert-butyldiphenylsilyloxy-6,6-divinyl-3-hydroxynona-1-en

: 503000-40-6
C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/ol034020s

Reference yield:

: 503000-50-8
6-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-6-vinyl-octa-2,7-dienoic acid ethyl ester

: 503000-40-6
C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

Guidance literature:: Multi-step reaction with 5 steps

1: 100 percent / DIBAl-H / tetrahydrofuran; hexane / 0.5 h / 0 °C

2: 92 percent / L-(+)-DIPT; molecular sieves 4 Angstroem; TBHP / Ti(i-PrO)4 / CH₂Cl₂ / -25 - 20 °C

3: 95 percent / triphenylphosphine; I₂; imidazole / benzene / 0.5 h / 20 °C

4: 96 percent / Zn; acetic acid / 0.5 h / 50 °C

5: 98 percent / Et₃N / CH₂Cl₂ / 0.5 h / 20 °C

With 1H-imidazole; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; 4 A molecular sieve; iodine; diisobutylaluminium hydride; acetic acid; triethylamine; triphenylphosphine; zinc; titanium(IV) isopropylate; In tetrahydrofuran; hexane; dichloromethane; benzene; 2: Katsuki-Sharpless asymmetric epoxidation;
DOI:10.1021/ol034020s

Reference yield:

: 215251-69-7
4-(tert-butyldiphenylsilyloxy)-N-methoxy-N-methylbutanamide

: 503000-40-6
C₂₇H₃₆SiO₂C₂H₄SiC₃H₈

Guidance literature:: Multi-step reaction with 15 steps

1: 63 percent / t-BuLi / tetrahydrofuran; pentane / -78 - 20 °C

2: 96 percent / NaH / 1,2-dimethoxy-ethane; various solvent(s) / 6 h / Heating

3: 99 percent / DIBAL-H / tetrahydrofuran; hexane / 0.5 h / 0 °C

4: 81 percent / Hg(OAc)2 / 24 h / Heating

5: 81 percent / triisobutylaluminum / CH₂Cl₂; hexane / 1 h / 20 °C

6: 14.35 g / n-Bu₃P / tetrahydrofuran / 14 h / 20 °C

7: 91 percent / H₂O₂ / tetrahydrofuran / 1 h / 20 °C

8: 100 percent / aq. HCl / ethanol / 2 h / 20 °C

9: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 0.5 h / 20 °C

10: 89 percent / benzene / 5 h / Heating

11: 100 percent / DIBAl-H / tetrahydrofuran; hexane / 0.5 h / 0 °C

12: 92 percent / L-(+)-DIPT; molecular sieves 4 Angstroem; TBHP / Ti(i-PrO)4 / CH₂Cl₂ / -25 - 20 °C

13: 95 percent / triphenylphosphine; I₂; imidazole / benzene / 0.5 h / 20 °C

14: 96 percent / Zn; acetic acid / 0.5 h / 50 °C

15: 98 percent / Et₃N / CH₂Cl₂ / 0.5 h / 20 °C

With 1H-imidazole; hydrogenchloride; tert.-butylhydroperoxide; oxalyl dichloride; L-(+)-diisopropyl tartrate; tributylphosphine; 4 A molecular sieve; mercury(II) diacetate; dihydrogen peroxide; iodine; tert.-butyl lithium; triisobutylaluminum; sodium hydride; diisobutylaluminium hydride; acetic acid; dimethyl sulfoxide; triethylamine; triphenylphosphine; zinc; titanium(IV) isopropylate; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; hexane; dichloromethane; pentane; benzene; 2: Horner-Emmons reaction / 10: Wittig reaction / 12: Katsuki-Sharpless asymmetric epoxidation;
DOI:10.1021/ol034020s