(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

Base Information

Chemical Name:(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)
CAS No.:162879-81-4
Molecular Formula:C₆₃H₆₄O₁₃P₂
Molecular Weight:1091.14
Hs Code.:

Synonyms:(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

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Chemical Property of (-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

Chemical Property:

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Technology Process of (-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

There total 10 articles about (-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphorous acid dibenzyl ester (1R,2S,3S,4R,5S,6R)-2,3,5-tris-benzyloxy-6-(bis-benzyloxy-phosphanyloxy)-4-(4-methoxy-benzyloxy)-cyclohexyl ester

: 162879-81-4
(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - 20 ℃; for 2h;
DOI:10.1039/b200585a

Reference yield:

: 100-39-0
benzyl bromide

: 162879-81-4
(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

Guidance literature:: Multi-step reaction with 5 steps

1: 75 percent / Bu₂SnO; Bu₄NBr / acetonitrile / 21 h / Heating

2: iPr₂NEt / (Ph₃P)3RhCl / aq. ethanol; toluene / 2 h / Heating

3: 0.013 g / AcCl / methanol; CH₂Cl₂ / 0.5 h / 20 °C

4: 1H-tetrazole / CH₂Cl₂ / 5 h / 20 °C

5: MCPBA / CH₂Cl₂ / 2 h / -78 - 20 °C

With 1H-tetrazole; tetrabutylammomium bromide; di(n-butyl)tin oxide; N-ethyl-N,N-diisopropylamine; acetyl chloride; 3-chloro-benzenecarboperoxoic acid; Wilkinson's catalyst; In methanol; ethanol; dichloromethane; toluene; acetonitrile;
DOI:10.1039/b200585a

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 162879-81-4
(-)-1D-2,3,4-tri-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol 4,5-bis(dibenzylphosphate)

Guidance literature:: Multi-step reaction with 7 steps

1: 82 percent / NaH / dimethylformamide / 0 - 20 °C

2: 82 percent / AcCl / methanol; CH₂Cl₂ / 1 h / 20 °C

3: 75 percent / Bu₂SnO; Bu₄NBr / acetonitrile / 21 h / Heating

4: iPr₂NEt / (Ph₃P)3RhCl / aq. ethanol; toluene / 2 h / Heating

5: 0.013 g / AcCl / methanol; CH₂Cl₂ / 0.5 h / 20 °C

6: 1H-tetrazole / CH₂Cl₂ / 5 h / 20 °C

7: MCPBA / CH₂Cl₂ / 2 h / -78 - 20 °C

With 1H-tetrazole; tetrabutylammomium bromide; sodium hydride; di(n-butyl)tin oxide; N-ethyl-N,N-diisopropylamine; acetyl chloride; 3-chloro-benzenecarboperoxoic acid; Wilkinson's catalyst; In methanol; ethanol; dichloromethane; N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1039/b200585a