C₃₆H₅₀N₂O₃SSi

Base Information Edit

Chemical Name:C₃₆H₅₀N₂O₃SSi
CAS No.:211759-07-8
Molecular Formula:C₃₆H₅₀N₂O₃SSi
Molecular Weight:618.956
Hs Code.:
Mol file:211759-07-8.mol

C<sub>36</sub>H<sub>50</sub>N<sub>2</sub>O<sub>3</sub>SSi

Synonyms:C₃₆H₅₀N₂O₃SSi

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Chemical Property of C₃₆H₅₀N₂O₃SSi Edit

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Technology Process of C₃₆H₅₀N₂O₃SSi

There total 15 articles about C₃₆H₅₀N₂O₃SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 211758-65-5
C₄₂H₅₄N₂O₅S₂Si

: 211759-07-8
C₃₆H₅₀N₂O₃SSi

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; In methanol; for 2h; Ambient temperature;
DOI:10.1021/jo9801770

Reference yield:

: 5470-66-6
2-methyl-4-nitropyridine N-oxide

: 211759-07-8
C₃₆H₅₀N₂O₃SSi

Guidance literature:: Multi-step reaction with 12 steps

1: 84 percent / PCl₃ / CHCl₃ / 40 h / Ambient temperature

2: 50 percent / NaOH / dimethylsulfoxide / 0.5 h / 15 - 20 °C

3: 83 percent / methanol / Ambient temperature

4: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 1 h, then -78 to 0 deg C, 45 min, 2.) THF, hexane, 1.25 h

5: 94 percent / Na/Hg, Na₂HPO₄ / methanol / 2.5 h / Ambient temperature

6: 89 percent / OsO₄, NaIO₄ / tetrahydrofuran / 7 h / 0 - 20 °C

7: 81 percent / tetrahydrofuran / 4.5 h / -50 - 20 °C

8: 95 percent / Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 6.5 h / Ambient temperature

9: 97 percent / m-CPBA / CH₂Cl₂ / 3 h / Ambient temperature

10: 1.) p-TsCl, Et₃N / 1.) CH₂Cl₂, -50 deg C, 5 h, 2.) DMF, room temp., 12 h

11: 1.) NaHMDS, 2.) Pd₂(dba)3*CHCl₃, 1,2-bis(diphenylphosphino)ethane / 1.) THF, -78 deg C, 70 min, 2.) THF, reflux, 4 h

12: 66 percent / Na/Hg, Na₂HPO₄ / methanol / 2 h / Ambient temperature

With dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hydroxide; sodium periodate; disodium hydrogenphosphate; sodium amalgam; osmium(VIII) oxide; n-butyllithium; sodium hexamethyldisilazane; triethylamine; p-toluenesulfonyl chloride; 3-chloro-benzenecarboperoxoic acid; 1,2-bis-(diphenylphosphino)ethane; phosphorus trichloride; In tetrahydrofuran; methanol; dichloromethane; chloroform; dimethyl sulfoxide;
DOI:10.1021/jo9801770

Reference yield:

: 13508-96-8
2-methyl-4-nitro-pyridine

: 211759-07-8
C₃₆H₅₀N₂O₃SSi

Guidance literature:: Multi-step reaction with 11 steps

1: 50 percent / NaOH / dimethylsulfoxide / 0.5 h / 15 - 20 °C

2: 83 percent / methanol / Ambient temperature

3: 1.) n-BuLi / 1.) THF, hexane, -78 deg C, 1 h, then -78 to 0 deg C, 45 min, 2.) THF, hexane, 1.25 h

4: 94 percent / Na/Hg, Na₂HPO₄ / methanol / 2.5 h / Ambient temperature

5: 89 percent / OsO₄, NaIO₄ / tetrahydrofuran / 7 h / 0 - 20 °C

6: 81 percent / tetrahydrofuran / 4.5 h / -50 - 20 °C

7: 95 percent / Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 6.5 h / Ambient temperature

8: 97 percent / m-CPBA / CH₂Cl₂ / 3 h / Ambient temperature

9: 1.) p-TsCl, Et₃N / 1.) CH₂Cl₂, -50 deg C, 5 h, 2.) DMF, room temp., 12 h

10: 1.) NaHMDS, 2.) Pd₂(dba)3*CHCl₃, 1,2-bis(diphenylphosphino)ethane / 1.) THF, -78 deg C, 70 min, 2.) THF, reflux, 4 h

11: 66 percent / Na/Hg, Na₂HPO₄ / methanol / 2 h / Ambient temperature

With dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hydroxide; sodium periodate; disodium hydrogenphosphate; sodium amalgam; osmium(VIII) oxide; n-butyllithium; sodium hexamethyldisilazane; triethylamine; p-toluenesulfonyl chloride; 3-chloro-benzenecarboperoxoic acid; 1,2-bis-(diphenylphosphino)ethane; In tetrahydrofuran; methanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo9801770