tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese

Base Information

• Chemical Name: tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese
• CAS No.: 59592-97-1
• Molecular Formula: C₁₅H₁₁MnO₃
• Molecular Weight: 294.189
• Mol file: 59592-97-1.mol

Synonyms:tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese

Chemical Property of tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese

Chemical Property:

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Technology Process of tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese

There total 2 articles about tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tricarbonyl(η(5)-1-chloro-1-5-cyclohexadienyl)manganese (182004-27-9) + tributylphenylstannane (960-16-7) → tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese (59592-97-1) + [Mn(CO)3(η5-(1-COPh-cyclohexadienyl))] (530151-19-0)

Guidance literature:

With Pd₂(dba)3; SbPh₃; In N,N-dimethyl-formamide; (N2); using Schlenk techniques; addn. of Pd2(dba)3 and SbPh3 to soln. ofMn(CO)3(ClC6H6) in anhyd. degassed DMF, after 5 min addn. of PhSnBu3 at room temp., stirring for 4.5 h at room temp.; pouring into 50 ml of cold ice water, extn. twice with pentane, washing with water of combined org. phases, drying over MgSO4, filtration, evapn. under reduced pressure, flash chromy. on silica gel (pentane), elem. anal.;

DOI:10.1021/om021017o

Reference yield: 52.0%

tricarbonyl(η(5)-1-chloro-1-5-cyclohexadienyl)manganese (182004-27-9) + tributylphenylstannane (960-16-7) → tricarbonyl(1-phenyl-η5-cyclohexadienyl)manganese (59592-97-1)

Guidance literature:

With AsPh₃; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In N,N-dimethyl-formamide; react. Mn complex with PhSnBu3 in the presence of Pd2(dba)3 and AsPh3 inDMF at room temp. for 23 h;

DOI:10.1021/om000831d

upstream raw materials:

tricarbonyl(η(5)-1-chloro-1-5-cyclohexadienyl)manganese

tributylphenylstannane