Technology Process of 3,6-bis(hexyloxy)-1,4-dimercapto-2,5-diphosphinobenzene
There total 6 articles about 3,6-bis(hexyloxy)-1,4-dimercapto-2,5-diphosphinobenzene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium aluminium tetrahydride;
In
diethyl ether;
at -78 - 20 ℃;
Inert atmosphere;
Schlenk technique;
DOI:10.1002/chem.201402561
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: potassium hydroxide; bromine / Inert atmosphere
2.1: tert.-butyl lithium / diethyl ether / 5 h / -78 - -40 °C / Inert atmosphere; Schlenk technique
2.2: -78 - 20 °C / Inert atmosphere; Schlenk technique
3.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 - 0 °C / Inert atmosphere; Schlenk technique
3.2: -78 - 20 °C / Inert atmosphere; Schlenk technique
4.1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere; Schlenk technique
5.1: lithium aluminium tetrahydride / diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique
With
lithium aluminium tetrahydride; n-butyllithium; bromine; tert.-butyl lithium; diisopropylamine; potassium hydroxide;
In
tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/chem.201402561
- Guidance literature:
-
Multi-step reaction with 2 steps
1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere; Schlenk technique
2: lithium aluminium tetrahydride / diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique
With
lithium aluminium tetrahydride; n-butyllithium; diisopropylamine;
In
tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/chem.201402561
