4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

Base Information

Chemical Name:4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)
CAS No.:1618089-35-2
Molecular Formula:C₃₄H₄₀O₄P₂S₂
Molecular Weight:638.769
Hs Code.:

Synonyms:4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

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Chemical Property of 4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

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Technology Process of 4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

There total 7 articles about 4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1618089-31-8
3,6-bis(hexyloxy)-1,4-dimercapto-2,5-diphosphinobenzene

: 100-07-2
4-methoxy-benzoyl chloride

: 1618089-35-2
4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

Guidance literature:: With triethylamine; In toluene; at 110 ℃; for 17h; Inert atmosphere; Schlenk technique;
DOI:10.1002/chem.201402561

Reference yield:

: 1618089-29-4
S,S'-(2,5-bis(hexyloxy)-1,4-phenylene) O,O,O',O'-tetraisopropyldiphosphorothioate

: 1618089-35-2
4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

Guidance literature:: Multi-step reaction with 3 steps

1: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere; Schlenk technique

2: lithium aluminium tetrahydride / diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique

3: triethylamine / toluene / 17 h / 110 °C / Inert atmosphere; Schlenk technique

With lithium aluminium tetrahydride; n-butyllithium; triethylamine; diisopropylamine; In tetrahydrofuran; diethyl ether; hexane; toluene;
DOI:10.1002/chem.201402561

Reference yield:

: 1618089-30-7
tetraisopropyl (2,5-bis(hexyloxy)-3,6-dimercapto-1,4-phenylene)bisphosphonate

: 1618089-35-2
4,8-bis(hexyloxy)-2,6-bis(4-methoxyphenyl)benzo[1,2-d:4,5-d']bis([1,3]thiaphosphole)

Guidance literature:: Multi-step reaction with 2 steps

1: lithium aluminium tetrahydride / diethyl ether / -78 - 20 °C / Inert atmosphere; Schlenk technique

2: triethylamine / toluene / 17 h / 110 °C / Inert atmosphere; Schlenk technique

With lithium aluminium tetrahydride; triethylamine; In diethyl ether; toluene;
DOI:10.1002/chem.201402561