chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)

Base Information

• Chemical Name: chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)
• CAS No.: 1425266-16-5
• Molecular Formula: C₁₄H₁₇AuClP
• Molecular Weight: 448.682
• Mol file: 1425266-16-5.mol

Synonyms:chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)

Chemical Property of chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)

There total 1 articles about chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + 2,3,4,5-tetramethyl-1-phenylphosphole (112549-07-2) → chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I) (1425266-16-5)

Guidance literature:

In dichloromethane; at 22 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om301244m

Reference yield: 78.0%

silver hexafluoroantimonate (26042-64-8) + chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I) (1425266-16-5) + acetonitrile (75-05-8,26809-02-9) → [(1-phenyl-2,3,4,5-tetramethylphosphole)(acetonitrile)]SbF6 (1425266-27-8)

Guidance literature:

at 25 ℃; for 24h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1021/om301244m

Reference yield: 66.0%

chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I) (1425266-16-5) + silver(I) triflimide (189114-61-2) → Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf2 (1425266-23-4)

Guidance literature:

In dichloromethane; at 25 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om301244m

upstream raw materials:

chloro(dimethylsulfide) gold(I)

2,3,4,5-tetramethyl-1-phenylphosphole

Downstream raw materials:

Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂

[(1-phenyl-2,3,4,5-tetramethylphosphole)(acetonitrile)]SbF₆