3--1-phenyl-1-propene

Base Information

• Chemical Name: 3--1-phenyl-1-propene
• CAS No.: 115270-07-0
• Molecular Formula: C₁₉H₂₇NO₄
• Molecular Weight: 333.428
• Mol file: 115270-07-0.mol

Synonyms:3--1-phenyl-1-propene

Chemical Property of 3--1-phenyl-1-propene

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 3--1-phenyl-1-propene

There total 10 articles about 3--1-phenyl-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

N,N-bis(tert-butoxycarbonyl)allylamine (115269-99-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 3--1-phenyl-1-propene (115270-07-0)

Guidance literature:

With silver(I) acetate; palladium diacetate; In dimethyl sulfoxide; at 130 ℃; for 4h; Reagent/catalyst; Solvent; Temperature; regioselective reaction; Sealed tube;

DOI:10.1002/cctc.201403019

Reference yield: 87.0%

iminodicarboxylic acid di-tert-butyl ester (51779-32-9) + (E)-methyl cinnamyl carbonate (87802-71-9,85217-69-2) → (-)-di-tert-butyl [(1S)-1-phenylprop-2-en-1-yl]imidodicarbonate (913344-44-2) + 3--1-phenyl-1-propene (115270-07-0)

Guidance literature:

(E)-methyl cinnamyl carbonate; With C₅₀H₅₂IrNO₄P⁽¹⁺⁾*CF₃O₃S^(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; for 0.0833333h; Inert atmosphere; Schlenk technique;

iminodicarboxylic acid di-tert-butyl ester; In tetrahydrofuran; at 50 ℃; for 2h; enantioselective reaction; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejoc.201501333

Reference yield: 81.0%

2-phenyl[1,3,2]dioxaborolane (4406-72-8) + N,N-bis(tert-butoxycarbonyl)allylamine (115269-99-3) → 3--1-phenyl-1-propene (115270-07-0)

Guidance literature:

With oxygen; palladium diacetate; copper(II) bis(trifluoromethanesulfonate); In N,N-dimethyl acetamide; at 40 ℃; for 48h; regioselective reaction;

DOI:10.1021/acs.orglett.0c00061

upstream raw materials:

Cinnamyl acetate

iminodicarboxylic acid di-tert-butyl ester

ethyl (E)-3-phenyl-2-propenyl carbonate

Phenyl triflate

Downstream raw materials:

tert-butyl N-[(2E)-3-phenylprop-2-en-1-yl]carbamate