1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate

Base Information

• Chemical Name: 1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate
• CAS No.: 1294451-45-8
• Molecular Formula: C₁₉H₂₂ClN₂*ClO₄
• Molecular Weight: 413.301
• Mol file: 1294451-45-8.mol

Synonyms:1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate

Chemical Property of 1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate

There total 1 articles about 1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-bis-(4-tolyl)acetamide (32047-89-5) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate (1294451-45-8)

Guidance literature:

N,N-bis-(4-tolyl)acetamide; N,N-dimethyl-formamide; With trichlorophosphate; at 20 ℃; Cooling;

With perchloric acid; In water;

DOI:10.3998/ark.5550190.0013.325

Reference yield:

1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate (1294451-45-8) + Methyl thioglycolate (2365-48-2) → methyl 2-[bis(4-tolyl)amino]thiophen-5-carboxylate (1065122-93-1)

Guidance literature:

With sodium methylate; In acetonitrile; at 20 ℃; pH=> 9;

DOI:10.3998/ark.5550190.0013.325

Reference yield:

1-chloro-1-[bis-(4-tolyl)amino]-propene-3-dimethylmethiniminium perchlorate (1294451-45-8) → 2-methoxycarbonyl-6-methyl-9-(4-tolyl)-thieno[2,3-b]quinolinium perchlorate (1379764-17-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: sodium methylate / acetonitrile / 20 °C / pH > 9

2.1: trichlorophosphate / 0.33 h / 60 °C / Cooling

2.2: Cooling

With sodium methylate; trichlorophosphate; In acetonitrile;

DOI:10.3998/ark.5550190.0013.325

upstream raw materials:

N,N-bis-(4-tolyl)acetamide

N,N-dimethyl-formamide

Downstream raw materials:

methyl 2-[bis(4-tolyl)amino]thiophen-5-carboxylate

2-methoxycarbonyl-6-methyl-9-(4-tolyl)-thieno[2,3-b]quinolinium perchlorate