(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

Base Information

Chemical Name:(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester
CAS No.:867039-46-1
Molecular Formula:C₁₈H₂₅NO₄S
Molecular Weight:351.467
Hs Code.:

Synonyms:(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

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Chemical Property of (E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

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Technology Process of (E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

There total 4 articles about (E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 475292-56-9
4-methyl-N-(3-methylbut-2-en-1-yl)-N-(3-oxopropyl)benzenesulfonamide

: 867039-46-1
(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

Guidance literature:: In dichloromethane; at 25 ℃; for 18h;
DOI:10.1016/j.tetlet.2005.08.002

Reference yield:

: 13379-98-1
3-[N-(4-methylphenylsulfonyl)amino]propan-1-ol

: 867039-46-1
(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / Cs₂CO₃ / acetonitrile / 18 h / 25 °C

2: 67 percent / PCC; Celite / CH₂Cl₂ / 2 h / 25 °C

3: 65 percent / CH₂Cl₂ / 18 h / 25 °C

With Celite; caesium carbonate; pyridinium chlorochromate; In dichloromethane; acetonitrile; 3: Wittig reaction;
DOI:10.1016/j.tetlet.2005.08.002

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 867039-46-1
(E)-5-[N-(3-methylbut-2-enyl)-N-(toluene-4-sulfonyl)amino]pent-2-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 68 percent / Et₃N / CH₂Cl₂ / 1 h / 0 - 25 °C

2: 93 percent / Cs₂CO₃ / acetonitrile / 18 h / 25 °C

3: 67 percent / PCC; Celite / CH₂Cl₂ / 2 h / 25 °C

4: 65 percent / CH₂Cl₂ / 18 h / 25 °C

With Celite; caesium carbonate; triethylamine; pyridinium chlorochromate; In dichloromethane; acetonitrile; 4: Wittig reaction;
DOI:10.1016/j.tetlet.2005.08.002