methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

Base Information

Chemical Name:methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate
CAS No.:101916-98-7
Molecular Formula:C₃₀H₃₂Br₂O₆
Molecular Weight:648.388
Hs Code.:

Synonyms:methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

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Chemical Property of methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

There total 10 articles about methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101916-94-3
tert-butyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-D-threo-hept-2-en-6-ulosonate

: 101916-98-7
methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / CF₃COOH / CH₂Cl₂ / 0 °C

2: 1.) LDA; 2.) LDA / 2.) -78 deg C

With trifluoroacetic acid; lithium diisopropyl amide; In dichloromethane;
DOI:10.1021/ja00271a049

Reference yield:

: 160549-10-0
2,3,5-tri-O-benzyl-D-arabinofuranose

: 101916-98-7
methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / CH₂Cl₂ / 25 °C

2: DMSO/(COCl)2, EtN₃

3: 93 percent / CF₃COOH / CH₂Cl₂ / 0 °C

4: 1.) LDA; 2.) LDA / 2.) -78 deg C

With oxalyl dichloride; dimethyl sulfoxide; trifluoroacetic acid; lithium diisopropyl amide; ethyl azide; In dichloromethane;
DOI:10.1021/ja00271a049

Reference yield:

: 221103-29-3
(E)-(4R,5R,6R)-4,5,7-Tris-benzyloxy-6-hydroxy-hept-2-enoic acid tert-butyl ester

: 101916-98-7
methyl (Z)-4,5,7-tri-O-benzyl-2,3-dideoxy-6-C-(dibromomethyl)-L-xylo-hept-2-enonate

Guidance literature:: Multi-step reaction with 3 steps

1: DMSO/(COCl)2, EtN₃

2: 93 percent / CF₃COOH / CH₂Cl₂ / 0 °C

3: 1.) LDA; 2.) LDA / 2.) -78 deg C

With oxalyl dichloride; dimethyl sulfoxide; trifluoroacetic acid; lithium diisopropyl amide; ethyl azide; In dichloromethane;
DOI:10.1021/ja00271a049