Acetic acid, 2,2,2-trifluoro-, 3-nitrophenyl ester

Base Information

• Chemical Name: Acetic acid, 2,2,2-trifluoro-, 3-nitrophenyl ester
• CAS No.: 1737-40-2
• Molecular Formula: C₈H₄F₃NO₄
• Molecular Weight: 235.119
• Mol file: 1737-40-2.mol

Synonyms:3-nitrophenyl trifluoroacetates

Chemical Property of Acetic acid, 2,2,2-trifluoro-, 3-nitrophenyl ester

Chemical Property:

• Melting Point: 41.4-46 °C
• Boiling Point: 92 °C(Press: 1.15 Torr)
• Density: 1.514±0.06 g/cm3(Predicted)

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Acetic acid, 2,2,2-trifluoro-, 3-nitrophenyl ester

There total 4 articles about Acetic acid, 2,2,2-trifluoro-, 3-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-nitrophenyldiazonium tetrafluoroborate (586-36-7) + trifluoroacetic acid (76-05-1) → 3-fluoro-1-nitrobenzene (402-67-5) + 3-nitrophenyl trifluoroacetates (1737-40-2)

Guidance literature:

Heating;

DOI:10.1246/bcsj.75.789

Reference yield:

3-nitro-aniline (99-09-2) + 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate (174899-65-1) → 3-nitrophenyl trifluoroacetates (1737-40-2) + nitrobenzene (98-95-3,26969-40-4)

Guidance literature:

3-nitro-aniline; 3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate; With tetrafluoroboric acid; sodium nitrite; at 0 - 20 ℃; for 12.5h;

at 30 ℃;

DOI:10.1016/S0022-1139(00)00337-7

Reference yield:

meta-nitrophenol (554-84-7) + trifluoroacetic anhydride (407-25-0) → 3-nitrophenyl trifluoroacetates (1737-40-2)

Guidance literature:

upstream raw materials:

meta-nitrophenol

trifluoroacetic anhydride

3-nitro-aniline

3-ethyl-1-methyl-1H-imidazol-3-ium 2,2,2-trifluoroacetate

Downstream raw materials:

meta-nitrophenol

trifluoroacetic acid

2,4-Dinitrophenol

Refernces

• 1、 -. "Isotopically enriched N-substituted piperazines and methods for the preparation thereof". Page/Page column 14-15. . Retrieved 2008/06/13.
• 2、 Canning, Peter S. J.,Maskill, Howard,McCrudden, Katharine,Sexton, Brian. "A product analytical study of the thermal and photolytic decomposition of some arenediazonium salts in solution". . p. 789 - 800. Retrieved 2007/10/03.