586-36-7

Basic information

• Product Name: Benzenediazonium, 3-nitro-, tetrafluoroborate(1-)
• CAS NO: 586-36-7
• Molecular Formula: C6H4N3O2.BF4
• Molecular Weight: 236.921
• Mol File: 586-36-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenediazonium, 3-nitro-, tetrafluoroborate(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenediazonium, 3-nitro-, tetrafluoroborate(1-)(586-36-7)
• EPA Substance Registry System: Benzenediazonium, 3-nitro-, tetrafluoroborate(1-)(586-36-7)

Safety Data

• Hazardous Substances Data: 586-36-7(Hazardous Substances Data)

Upstream product

• 99-09-2 3-nitro-aniline 
• 462-34-0 boron trifluoride-tetrahydrofuran complex 
• 13755-29-8 sodium tetrafluoroborate 

Downstream Products

• 32578-25-9 trifluoromethanesulfonic acid 3-nitrophenyl ester 
• 99-61-6 3-nitro-benzaldehyde 
• 98-95-3 nitrobenzene 
• 119276-93-6 (E)-3-nitro-benzenediazo hydroxide; sodium-salt 
• 112148-14-8 2,5-Dimethoxy-3'-nitro-biphenyl 
• 32488-52-1 3-deuterionitrobenzene 
• 402-67-5 3-fluoro-1-nitrobenzene 
• 87014-29-7 1-nitro-3-(2,2,2-trifluoroethoxy)benzene 
• 621-52-3 1-ethoxy-3-nitrobenzene 
• 4103-30-4 3,3'-dinitroazobenzene 
• 99-65-0 meta-dinitrobenzene 
• 3837-55-6 4-(3-nitrophenylazo)-N,N-dimethylaniline 
• 958-96-3 3,3'-dinitro-1,1'-biphenyl 
• 2113-58-8 3-nitro-1,1'-biphenyl 

Relevant articles and documents

Copper-mediated tandem ring-opening/cyclization reactions of cyclopropanols with aryldiazonium salts: Synthesis of: N -arylpyrazoles

A general method for the synthesis of structurally diverse N-arylpyrazoles from readily available cyclopropanols and aryldiazonium salts is disclosed. The reaction was conducted at room temperature within minutes with a broad substrate scope and excellent regioselectivity.

Copper(I)-promoted trifluoromethylthiolation of arenediazonium salts with AgSCF3

An efficient method for trifluoromethylthiolation of arenediazonium salts has been developed in mild conditions with a stable and convenient AgSCF3. It provides a straightforward and convenient way for the synthesis of trifluoromethylthiolated compound from diazonium salts in moderate to good yields.

Palladium catalyzed stereocontrolled synthesis of C-aryl glycosides using glycals and arenediazonium salts at room temperature

A stereocontrolled synthesis of aryl-C-glycosides was achieved using glycals and aryldiazonium salts in the presence of palladium acetate. A wide range of glycals including d-glucal, d-galactal, l-rhamnal, d-xylal and d-ribal underwent C-arylation at the anomeric carbon in the presence of different aryldiazonium tetrafluoroborates and gave synthetically useful 2,3-deoxy-3-keto-α-aryl-C-glycosides in good to excellent yields. Broad substrate scope, simple operation and room temperature reactions make this protocol very attractive in organic synthesis.