Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S)

Base Information

• Chemical Name: Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S)
• CAS No.: 1257217-06-3
• Molecular Formula: C₁₆H₄₅NO₆SSi₅Sn₄
• Molecular Weight: 994.87
• Mol file: 1257217-06-3.mol

Synonyms:Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S)

Chemical Property of Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S)

Chemical Property:

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Technology Process of Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S)

There total 1 articles about Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

carbon oxide sulfide (463-58-1) + bis(bis(trimethylsilyl)amido)tin(II) (55147-78-9) → tin (7440-31-5) + Sn4(μ4-O)(μ2-OSiMe3)5(η1-N=C=S) (1257217-06-3)

Guidance literature:

In hexane; byproducts: ((CH3)3Si)2NH, (CH3)3SiOSi(CH3)3, (CH3)3SiNCS; (Ar); soln. of tin complex in hexane was placed in bomb at -100°C, OCS was added, stirred and warmed to 25°C, stirred overnight; cooled to -78°C excess OCS was removed in vac., filtered, washed with pentane, crystal were obtained from filtrate, elem. anal.;

DOI:10.1021/ic101709q

upstream raw materials:

carbon oxide sulfide

bis(bis(trimethylsilyl)amido)tin(II)

Refernces