(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

Base Information

Chemical Name:(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole
CAS No.:123538-53-4
Molecular Formula:C₂₆H₃₀O₆S
Molecular Weight:470.587
Hs Code.:

Synonyms:(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

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Chemical Property of (3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

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Technology Process of (3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

There total 3 articles about (3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 56069-39-7
diethyl phenylsulfonylmethylphosphonate

: 123538-53-4
(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: 63 percent / diisopropylethylamine, LiCl / acetonitrile / 18 h

2: Pd(OAc)2, (i-C₃H₇O)3P / toluene / 18 h / 80 - 85 °C

With N-ethyl-N,N-diisopropylamine; lithium chloride; palladium diacetate; triisopropyl phosphite; In toluene; acetonitrile;
DOI:10.1021/ja00201a032

Reference yield:

: 23558-05-6
3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose

: 123538-53-4
(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: 63 percent / diisopropylethylamine, LiCl / acetonitrile / 18 h

2: Pd(OAc)2, (i-C₃H₇O)3P / toluene / 18 h / 80 - 85 °C

With N-ethyl-N,N-diisopropylamine; lithium chloride; palladium diacetate; triisopropyl phosphite; In toluene; acetonitrile;
DOI:10.1021/ja00201a032

Reference yield:

: 72047-94-0
[2-(acetoxymethyl)prop-2-enyl]trimethylsilane

: 123487-99-0
3-O-Benzyl-5,6-dideoxy-(E)-5,6-didehydro-1,2-O-isopropylidene-α-D-gluco-1,4-furanose

: 123538-53-4
(3aR,5R,6S,6aR)-5-((1S,2R)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

: 123488-09-5
(3aR,5R,6S,6aR)-5-((1R,2S)-2-Benzenesulfonyl-4-methylene-cyclopentyl)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: palladium diacetate; triisopropyl phosphite; In toluene; at 80 - 85 ℃; for 18h; Yield given. Yields of byproduct given;
DOI:10.1021/ja00201a032