72047-94-0Relevant articles and documents
A Short and Efficient Preparation of 2-Trimethylsilylmethyl-2-propen-1-ol
Agnel, Gilbert,Malacria, Max
, p. 687 - 688 (1989)
2-Trimethylsilylmethyl-2-propen-1-ol is efficiently prepared in 64percent overall yield starting from the cheap propargyl alcohol.
Radical cyclization of bromomethyldimethylsilyl propargyl ethers; A general method for the stereoselective synthesis of variously substituted trimethylenemethane (TMM) precursors
Bogen,Journet,Malacria
, p. 1215 - 1221 (1994)
The radical cyclization of bromomethyldimethylsilyl propargyl ethers allows the regio- and stereoselective preparation of variously substituted 2- trimethylsilylmethyl-2-propen-1-ol derivatives in good yields. After acetylation of the alcohol function, th
Preparation of 2-(trimethylsilyl)methyl-2-propen-1-ol derivatives by cobalt catalyzed sp2-sp3 coupling
Riaz, M. Tariq,Pohorilets, Ivanna,Hernandez, Jackson J.,Rios, Jeovanna,Totah, Nancy I.
supporting information, p. 2809 - 2812 (2018/06/15)
A practical, operationally simple preparation of 2-(trimethylsilyl)methyl-2-propen-1-ol derivatives is described. The cobalt catalyzed coupling of a protected vinyl halide with trimethylsilylmethylmagnesium chloride shows excellent functional group tolerance and provides these synthetically useful allyl silanes in good overall yield. By this method, the use of highly concentrated organolithium reagents, complex reaction protocols, and expensive starting materials is avoided.
Studies in the stereospecific synthesis of sesbanimide. Approaches to ring C
Willard, Nico,Wanner, Martin J.,Koomen, Gerrit-Jan,Pandit, Upendra K.
, p. 51 - 56 (2007/10/02)
Strating from 2-methylpropenol-2 and dimethyl 2,3-dimethylmaleate model approaches for the syntheses of ring C of sesbanimide and 13-oxo-sesbanimide have been developed