1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

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Chemical Name:1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine
CAS No.:849518-86-1
Molecular Formula:C₁₈H₂₉NSi
Molecular Weight:287.52
Hs Code.:

Synonyms:1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

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Chemical Property of 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

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Technology Process of 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

There total 2 articles about 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 5558-31-6
4-methyl-2-phenylpentanenitrile

: 18162-48-6
tert-butyldimethylsilyl chloride

: 849518-86-1
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

Guidance literature:: 4-methyl-2-phenylpentanenitrile; With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1002/anie.200461886

Reference yield:

: 140-29-4
phenylacetonitrile

: 849518-86-1
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium diisopropylamide / tetrahydrofuran; hexane / 0.75 h / -78 °C

1.2: 57 percent / tetrahydrofuran; hexane / -78 - 20 °C

2.1: diisopropylamine; n-BuLi / tetrahydrofuran; hexane / 0.08 h / -78 °C

2.2: 93 percent / tetrahydrofuran; hexane / -78 - 20 °C

With n-butyllithium; diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane;
DOI:10.1002/anie.200461886

Reference yield: 90.0%

: 849518-86-1
1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine

: 66-99-9
β-naphthaldehyde

: 960595-26-0
(2R,3S)-3-hydroxy-2-(2-methylpropyl)-3-(2-naphthyl)-2-phenylpropanenitrile

: C₂₃H₂₃NO

Guidance literature:: 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(4-methyl-2-phenyl-1-pentenylidene)silanamine; β-naphthaldehyde; With tetrachlorosilane; chiral bisphosphoramide catalyst; In dichloromethane; at -78 ℃; for 2h; Further stages.;
DOI:10.1021/ja077134y