benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Base Information

Chemical Name:benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate
CAS No.:1067891-60-4
Molecular Formula:C₁₇H₁₆Cl₂N₂O₃
Molecular Weight:367.232
Hs Code.:

Synonyms:benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Suppliers and Price of benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

There total 7 articles about benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1067891-66-0
benzyl (2,6-dichloropyridin-4-yl)(2-methylallyl)carbamate

: 1067891-60-4
benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 20 ℃; for 11h;
DOI:10.1021/ol801860s

Reference yield:

: 5398-44-7
2,6-dichloropyridine-4-carboxylic acid

: 1067891-60-4
benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Guidance literature:: Multi-step reaction with 5 steps

1.1: oxalyl dichloride / tetrahydrofuran / 2 h / Reflux

2.1: sodium azide / water; acetone / 0 - 10 °C

3.1: magnesium sulfate / toluene / 15 h / Reflux

4.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 0.08 h / 0 °C

4.2: 20 °C

5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 11 h / 0 - 20 °C

With sodium azide; oxalyl dichloride; tetra-(n-butyl)ammonium iodide; sodium hydride; magnesium sulfate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; water; acetone; toluene; 2.1: Curtius rearrangement;

Reference yield:

: 1067891-57-9
(2,6-dichloropyridin-4-yl)carbamic acid benzyl ester

: 1067891-60-4
benzyl (2,6-dichloropyridin-4-yl)((2-methyloxiran-2-yl)methyl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetra-(n-butyl)ammonium iodide; sodium hydride / tetrahydrofuran / 0.08 h / 0 °C

1.2: 20 °C

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 11 h / 0 - 20 °C

With tetra-(n-butyl)ammonium iodide; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;