1067891-57-9Relevant articles and documents
Titanocene(III)-catalyzed conversion of N-(epoxyalkyl)anilines into indolines
MacIejewski, John P.,Wipf, Peter
, p. 92 - 119 (2011/06/20)
Densely substituted indolines and azaindolines can be obtained by the titanocene(III) chloride catalyzed reductive opening of N-(oxiran-2-ylmethyl) anilines. The reaction optimization, substrate scope, and limitations are discussed, and a mechanistic pathway for the epoxideopening rearrangement is proposed. ARKAT-USA, Inc.