Bis-triphenyl phosphine iron tricarbonyl

Base Information

• Chemical Name: Bis-triphenyl phosphine iron tricarbonyl
• CAS No.: 14741-34-5
• Molecular Formula: C₃₉H₃₀FeO₃P₂
• Molecular Weight: 664.46
• Mol file: 14741-34-5.mol

Synonyms:IRON, TRICARBONYLBIS(TRIPHENYLPHOSPHINE);Bis-triphenyl phosphine iron tricarbonyl;14741-34-5;Iron, tricarbonylbis(triphenylphosphine)-;C39H30FeO3P2;SCHEMBL3002173;C39-H30-Fe-O3-P2;LS-84281

Chemical Property of Bis-triphenyl phosphine iron tricarbonyl

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 669.141080
• Heavy Atom Count: 45
• Complexity: 519

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH-]=O.[CH-]=O.[CH-]=O.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.[Fe+3]

Technology Process of Bis-triphenyl phosphine iron tricarbonyl

There total 189 articles about Bis-triphenyl phosphine iron tricarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

1,1-Diphenylethylene (530-48-3) + HFe(CO)2NO(P(C6H5)3) → bis(triphenylphosphine)dinitrosyliron + tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + Fe(CO)(NO)2(P(C6H5)3) + 1,1'-ethylidenebis-benzene (612-00-0)

Guidance literature:

In diethyl ether; to soln. FeH(CO)2(NO)(P(C6H5)3) in ether stoich. amt. 1,1-diphenyl ethylene added and soln. stirred for 15 min;

Reference yield: 43.0%

diiron nonacarbonyl (15321-51-4) + N-sulphinyl-p-bromoaniline (26516-62-1,52866-94-1) → iron pentacarbonyl (13463-40-6,37220-42-1) + tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + [Fe(triphenylphosphine)2(CO)2(4-BrC6H4NSO)] (85134-80-1)

Guidance literature:

With triphenylphosphine; In tetrahydrofuran; under N2, mixt. of Fe-complex, 4-BrC6H4NSO and PPh3 (molar ratio 1:1:2)in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;

Reference yield: 40.0%

diiron nonacarbonyl (15321-51-4) + 4-ClC6H4NSO (13165-68-9,52867-11-5) → iron pentacarbonyl (13463-40-6,37220-42-1) + tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + [Fe(triphenylphosphine)2(CO)2(4-ClC6H4NSO)] (85134-79-8)

Guidance literature:

With triphenylphosphine; In tetrahydrofuran; under N2, mixt. of Fe-complex, 4-ClC6H4NSO and PPh3 (molar ratio 1:1:2)in THF were stirred for 1-4 h at room temp.; filtered, recrystd. from ether-MeOH or CH2Cl2-hexane; elem. anal.;

upstream raw materials:

triphenylphosphine

triiron dodecarbonyl

iron

iron pentacarbonyl

Downstream raw materials:

iron(carbonyl)3((phenyl)3phosphine)Br₂

iron(II)(carbonyl)2((phenyl)3phosphine)2Cl₂

{Fe(CO)3(P(C₆H₅)3)2}⁽¹⁺⁾

tetracarbonyl(triphenylphosphine)iron