(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Base Information

Chemical Name:(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene
CAS No.:99315-77-2
Molecular Formula:C₂₅H₃₄O₃Si
Molecular Weight:410.629
Hs Code.:

Synonyms:(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Suppliers and Price of (4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

There total 5 articles about (4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 99333-00-3
(+)-(1R,6S,7S)-7-diphenyl-t-butylsiloxymethyl-8-oxabicyclo-<4.3.0>non-3-en-9-one

: 99315-77-2
(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Guidance literature:: With lithium borohydride; In tetrahydrofuran; at 25 ℃; for 85h;
DOI:10.1039/b902452b

Reference yield:

: 99315-76-1
(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone

: 99315-77-2
(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / AlCl₃ / CH₂Cl₂ / 168 h / 55 °C

2: LiBH₄ / tetrahydrofuran / Ambient temperature

With lithium borohydride; aluminium trichloride; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c39850000737

Reference yield:

: 92512-33-9
(3R,4S,5R)-5-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydroxydihydrofuran-2(3H)-one

: 99315-77-2
(4S,5R)-4-<(S)-2-diphenyl-t-butylsiloxy-1-hydroxyethyl>-5-hydroxymethylcyclohexene

Guidance literature:: Multi-step reaction with 4 steps

2: Raney nickel / tetrahydrofuran / Heating

3: 75 percent / AlCl₃ / CH₂Cl₂ / 168 h / 55 °C

4: LiBH₄ / tetrahydrofuran / Ambient temperature

With lithium borohydride; aluminium trichloride; nickel; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c39850000737