Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

Base Information

Chemical Name:Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)
CAS No.:1370365-60-8
Molecular Formula:C₂₄H₃₂ClOPTi
Molecular Weight:450.824
Hs Code.:

Synonyms:Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

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Chemical Property of Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

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Technology Process of Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

There total 1 articles about Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: 57542-89-9
di-tert-butyl-(2-hydroxyphenyl)phosphane

: 1370365-60-8
Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

Guidance literature:: With HN(C₂H₅)2; In tetrahydrofuran; Ar, Schlenk technique, glovebox; mixt. of Ti-complex and phosphine suspnd. in THF in Schlenk flask, amine added, stirred overnight; suspn. diluted (hexane), filtered through frit into Schlenk flask, solvent concd., flask left to stand at -20 °C overnight, supernatant removed (cannula), solid washed (hexane), dried (vac.); elem. anal.;
DOI:10.1002/ejic.201100968

Reference yield: 90.0%

: 1370365-60-8
Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

: 148354-27-2
triethylsilylium tetrakis(pentafluorophenyl), toluene adduct

: 1389319-07-6
Ti(η5-C5H5)2(OC6H4P(C(CH3)3)2)B(C6F5)4

Guidance literature:: In chlorobenzene; Ar, Schlenk technique, glovebox; sols. quickly mixed, soln. stand for 30min; soln. added dropwise to rapidly stirring hexane, procedure repeated 4 times, solid dissolved in C6H5Cl, layered with hexane, stand overnight, crystals removed, washed (hexane), dried (vac.); elem. anal.;
DOI:10.1002/ejic.201100968

Reference yield: 41.0%

: 74507-62-3
bis(pentamethylcyclopentadienyl)cobalt(II)

: 1370365-60-8
Ti(η5-C5H5)2Cl(OC6H4P(C(CH3)3)2)

: 75936-28-6
decamethylcobalticinium chloride

: 1389319-08-7
(C₅H₅)2TiOC₆H₄P(C(CH₃)3)2

Guidance literature:: With Co(C₅(CH₃)5)2; In benzene; byproducts: (C5(CH3)5)2CoCl; (Ar, Schlenk, glovebox) benzene was vac. transferred onto the mixt. of complexes at 0°C, the suspn. was stirred for 24 h; filtered, the solid was washed with benzene, solvent was removed under reduced pressure, ppt. was washed with several portions of hexane, dried in vac.;
DOI:10.1039/c2dt30168g