1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane

Base Information

• Chemical Name: 1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane
• CAS No.: 361525-33-9
• Molecular Formula: C₂₆H₄₉F₂NOSi₂
• Molecular Weight: 485.849
• Mol file: 361525-33-9.mol

Synonyms:1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane

Chemical Property of 1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane

There total 1 articles about 1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

Lithium-amino-di-tert-butylsilanolat (102729-04-4) + 2,4,6-tri-(tert-butyl)phenyltrifliorosilane (99789-89-6) → 1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane (361525-33-9)

Guidance literature:

In tetrahydrofuran; for 1h; Heating;

DOI:10.1002/1099-0682(200107)2001:7<1889::AID-EJIC1889>3.0.CO;2-6

Reference yield: 90.0%

1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane (361525-33-9) → 1-oxa-3-aza-2,4-disilacyclobutane (361525-34-0)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at 20 ℃; for 2h;

DOI:10.1002/1099-0682(200107)2001:7<1889::AID-EJIC1889>3.0.CO;2-6

Reference yield:

1-[aminodi(tert-butyl)]-3-{[2,4,6-tri(tert-butyl)phenyl]difluoro}1,3-disiloxane (361525-33-9) → 4,4-di(tert-butyl)-2-fluoro-2-[2,4,6-tri(tert-butyl)phenyl]-1-oxa-3-aza-2,4-disilacyclobutane

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / nBuLi / hexane; tetrahydrofuran / 2 h / 20 °C

2: 95 percent / nBuLi / hexane / 2 h / 20 °C

With n-butyllithium; In tetrahydrofuran; hexane;

DOI:10.1002/1099-0682(200107)2001:7<1889::AID-EJIC1889>3.0.CO;2-6

upstream raw materials:

Lithium-amino-di-tert-butylsilanolat

2,4,6-tri-(tert-butyl)phenyltrifliorosilane

Downstream raw materials:

1-oxa-3-aza-2,4-disilacyclobutane