2,4,6-tri-(tert-butyl)phenyltrifliorosilane

Base Information

• Chemical Name: 2,4,6-tri-(tert-butyl)phenyltrifliorosilane
• CAS No.: 99789-89-6
• Molecular Formula: C₁₈H₂₉F₃Si
• Molecular Weight: 330.509
• Mol file: 99789-89-6.mol

Synonyms:2,4,6-tri-(tert-butyl)phenyltrifliorosilane

Chemical Property of 2,4,6-tri-(tert-butyl)phenyltrifliorosilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,4,6-tri-(tert-butyl)phenyltrifliorosilane

There total 1 articles about 2,4,6-tri-(tert-butyl)phenyltrifliorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

1-bromo-2,4,6-tri-tert-butylbenzene (3975-77-7) → 2,4,6-tri-(tert-butyl)phenyltrifliorosilane (99789-89-6)

Guidance literature:

With n-butyllithium; silicon tetrafluoride; In hexane; Petroleum ether; -85 deg C to room temp.;

DOI:10.1016/0022-328X(85)80163-7

Reference yield: 96.0%

2,4,6-tri-(tert-butyl)phenyltrifliorosilane (99789-89-6) → (2,4,6-Tri-t-butylphenyl)silan (99789-90-9)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; r.t., 2 h; reflux, 2 h;

DOI:10.1016/0022-328X(85)80163-7

Reference yield: 93.0%

methyllithium (917-54-4) + 2,4,6-tri-(tert-butyl)phenyltrifliorosilane (99789-89-6) → difluoromethyl(2,4,6-tri-t-butylphenyl)silane (99789-91-0) + Dimethyl(2,4,6-tri-t-butylphenyl)fluorsilan

Guidance literature:

In diethyl ether; toluene; at -30 ℃;

DOI:10.1016/0022-328X(85)80163-7

upstream raw materials:

1-bromo-2,4,6-tri-tert-butylbenzene

Downstream raw materials:

difluoromethyl(2,4,6-tri-t-butylphenyl)silane

ethyldifluoro(2,4,6-tri-t-butylphenyl)silane

t-butyldifluoro(2,4,6-tri-t-butylphenyl)silane

difluoromesityl(2,4,6-tri-t-butylphenyl)silane