2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene

Base Information

• Chemical Name: 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene
• CAS No.: 220823-36-9
• Molecular Formula: C₂₂H₄₅NSSi
• Molecular Weight: 383.758
• Mol file: 220823-36-9.mol

Synonyms:2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene

Chemical Property of 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene

There total 1 articles about 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-(N,N-dimethylamino)-1-hexanol (1862-07-3) → 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene (220823-36-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 48percent aq. HBr / 84 h / Heating

1.2: NaOH / H₂O / 1.5 h / Heating

2.1: NaClO₂ / methanol; H₂O / 0.5 h / 25 °C

With sodium chlorite; In methanol; water; 1.1: Substitution / 1.2: Hydrolysis / 2.1: Dimerization;

DOI:10.1021/ja9940571

Reference yield: 36.0%

6-(N,N-dimethylamino)hexyl octyl fumarate (220823-39-2) + 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene (220823-36-9) → trans-1-[6-(N,N-dimethylamino)hexylthio]-2-(dimethyloctylsilyl)-4-(octanoxycarbonyl)-5-[6-(N,N-dimethylamino)hexanoxycarbonyl]-1-cyclohexene + trans-1-[6-(N,N-dimethylamino)hexylthio]-2-(dimethyloctylsilyl)-4-[6-(N,N-dimethylamino)hexanoxycarbonyl]-5-(octanoxycarbonyl)-1-cyclohexene

Guidance literature:

With 4-tert-Butylcatechol; In toluene; at 85 ℃; for 24h;

DOI:10.1021/ja9940571

Reference yield:

6-(N,N-dimethylamino)hexyl octyl fumarate (220823-39-2) + 2-[6-(N,N-dimethylamino)hexylthio]-3-dimethyloctylsilyl-1,3-butadiene (220823-36-9) → (1S,2S)-4-(6-Dimethylamino-hexylsulfanyl)-5-(dimethyl-octyl-silanyl)-cyclohex-4-ene-1,2-dicarboxylic acid 2-(6-dimethylamino-hexyl) ester 1-octyl ester + (1S,2S)-4-(6-Dimethylamino-hexylsulfanyl)-5-(dimethyl-octyl-silanyl)-cyclohex-4-ene-1,2-dicarboxylic acid 1-(6-dimethylamino-hexyl) ester 2-octyl ester

Guidance literature:

With 4-tert-Butylcatechol; In toluene; at 75 ℃; for 24h; Product distribution; other conditions;

DOI:10.1016/S0040-4039(98)02350-8

upstream raw materials:

6-(N,N-dimethylamino)-1-hexanol