1-phenyl-2-vinylcyclopropane

Base Information

• Chemical Name: 1-phenyl-2-vinylcyclopropane
• CAS No.: 17955-09-8
• Molecular Formula: C₁₁H₁₂
• Molecular Weight: 144.216
• Mol file: 17955-09-8.mol

Synonyms:Benzene,(2-ethenylcyclopropyl)-, trans-; Benzene, (2-vinylcyclopropyl)-, trans- (8CI);(trans-2-Phenylcyclopropyl)ethene; trans-1-Ethenyl-2-phenylcyclopropane;trans-1-Phenyl-2-vinylcyclopropane

Chemical Property of 1-phenyl-2-vinylcyclopropane

Chemical Property:

• Vapor Pressure: 0.397mmHg at 25°C
• Boiling Point: 203.4°Cat760mmHg
• Flash Point: 69.3°C
• PSA: 0.00000
• Density: 1.042g/cm³
• LogP: 2.97610

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-phenyl-2-vinylcyclopropane

There total 43 articles about 1-phenyl-2-vinylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

1-(trans-2-phenylcyclopropyl)-1-tributylstannylethene → (±)-trans-(2-vinylcyclopropyl)benzene (17955-08-7,17955-09-8,19159-61-6)

Guidance literature:

1-(trans-2-phenylcyclopropyl)-1-tributylstannylethene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1.75h;

With water; In tetrahydrofuran;

DOI:10.1021/jo047797n

Reference yield: 74.0%

Methyltriphenylphosphonium bromide (1779-49-3) + trans-2-phenylcyclopropanecarbaldehyde (34271-31-3) → (±)-trans-(2-vinylcyclopropyl)benzene (17955-08-7,17955-09-8,19159-61-6)

Guidance literature:

With n-butyllithium;

DOI:10.1021/jo00023a008

Reference yield: 44.0%

Methyltriphenylphosphonium bromide (1779-49-3) + rac-(1S,2R)-2-phenylcyclopropanecarbaldehyde (34271-30-2,34271-31-3,67074-44-6,79929-84-3,82263-48-7,82263-50-1) → cis-2-Phenyl-vinyl-cyclopropan (17955-08-7,17955-09-8,19159-61-6)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1002/chem.201503329

upstream raw materials:

(1S,2R)-1-formyl-2-phenylcyclopropane

Methyltriphenylphosphonium bromide

(1S,2R)-2-phenylcyclopropylmethanol

(2E)-3-phenyl-2-propen-1-ol

Downstream raw materials:

4-phenylcyclopentene

((1S,2S)-2-Vinyl-cyclopropyl)-benzene

(1E,3E)-1-phenyl-1,3-pentadiene

(±)-trans-(2-vinylcyclopropyl)benzene