{Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂

Base Information

• Chemical Name: {Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂
• CAS No.: 110014-69-2
• Molecular Formula: BF₄*CH₂Cl₂*C₅₂H₄₇Ir₂O₂P₄
• Molecular Weight: 1384.02
• Mol file: 110014-69-2.mol

Synonyms:{Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂

Chemical Property of {Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂

There total 4 articles about {Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*BF₄^(1-)*CH₂Cl₂={Ir₂(H)(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}BF₄*CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + cis-{Ir(CO)(Ph2PCH2PPh2)H2}2 → {Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}(1+)*BF4(1-)*CH2Cl2={Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}BF4*CH2Cl2 (110014-69-2)

Guidance literature:

With CH₂Cl₂; In dichloromethane; addn. of HBF4*Et2O to soln. of (Ir2(H)4(CO)2(Ph2PCH2PPh2)2) in CH2Cl2 in N2 atmosphere; stirring soln. for 24 h under very slow stream of N2; reduction of volume under N2; addn. of Et2O;; recrystn. from CH2Cl2/Et2O; elem. anal.;;

Reference yield:

cis-{Ir(CO)(Ph2PCH2PPh2)H2}2 + trityl tetrafluoroborate (341-02-6) → {Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}(1+)*BF4(1-)*CH2Cl2={Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}BF4*CH2Cl2 (110014-69-2)

Guidance literature:

With CH₂Cl₂; In dichloromethane; dropwise addn. of (C6H5)3CBF4 to soln. of (Ir2(H)4(CO)2(Ph2PCH2PPh2)2) in CH2Cl2; reduction of volume under N2 flow; addn. of Et2O;; elem. anal.;;

Reference yield:

tetrafluoroboric acid diethyl ether (67969-82-8) + {Ir2(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2} (110014-72-7) → {Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}(1+)*BF4(1-)*CH2Cl2={Ir2(H)(CO)2(H)2((C6H5)2PCH2P(C6H5)2)2}BF4*CH2Cl2 (110014-69-2)

Guidance literature:

In tetrahydrofuran; addn. of HBF4*Et2O to soln. of (Ir2(CO)2(μ-H)2(Ph2PCH2PPh2)2) in THF;; detn. by 1H-, 31P-NMR;;

upstream raw materials:

tetrafluoroboric acid diethyl ether

{Ir₂(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}

trans-{Ir2(H)2(CO)2(μ-H)2(bis(diphenylphosphino)methane)2}{BF4}2

N,N,N',N'-tetramethyl-1,8-diaminonaphthalene

Downstream raw materials:

{Ir₂(CO)2(H)2((C₆H₅)2PCH₂P(C₆H₅)2)2}

trans-{Ir2(H)2(CO)2(μ-H)2(bis(diphenylphosphino)methane)2}{BF4}2

Refernces