H-Gly-met-gly-OH

Base Information

• Chemical Name: H-Gly-met-gly-OH
• CAS No.: 51529-34-1
• Molecular Formula: C₉H₁₇N₃O₄S
• Molecular Weight: 263.318
• DSSTox Substance ID: DTXSID10199499
• Nikkaji Number: J372.587A
• Metabolomics Workbench ID: 82103
• ChEMBL ID: CHEMBL1221612
• Mol file: 51529-34-1.mol

Synonyms:H-GLY-MET-GLY-OH;51529-34-1;Gly-Met-Gly;Glycylmethionylglycine;glycyl-methionyl-glycine;Glycine, N-(N-glycyl-L-methionyl)-;2-[[(2S)-2-[(2-aminoacetyl)amino]-4-methylsulfanylbutanoyl]amino]acetic acid;(S)-2-(2-(2-Aminoacetamido)-4-(methylthio)butanamido)acetic acid;Gly-L-Met-Gly-OH;glycyl-l-methionyl-glycine;C9H17N3O4S;SCHEMBL7592083;CHEMBL1221612;DTXSID10199499;CHEBI:163883;C9-H17-N3-O4-S;MFCD00083705;2-[[(2S)-2-[(2-aminoacetyl)amino]-4-methylsulanylbutanoyl]amino]acetic acid

Chemical Property of H-Gly-met-gly-OH

Chemical Property:

• Vapor Pressure: 4.93E-19mmHg at 25°C
• Boiling Point: 565.5°Cat760mmHg
• Flash Point: 295.8°C
• PSA: 153.80000
• Density: 1.337g/cm³
• LogP: 0.76470
• Storage Temp.: -15°C
• XLogP3: -3.7
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 8
• Exact Mass: 263.09397721
• Heavy Atom Count: 17
• Complexity: 285

Purity/Quality:

99%+, ^*data from raw suppliers

H-GLY-MET-GLY-OH 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CSCCC(C(=O)NCC(=O)O)NC(=O)CN
• Isomeric SMILES: CSCC[C@@H](C(=O)NCC(=O)O)NC(=O)CN

Technology Process of H-Gly-met-gly-OH

There total 1 articles about H-Gly-met-gly-OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ glycyl-L-methionylglycine (51529-34-1)

Guidance literature:

With palladium; Hydrogenation;

Reference yield:

glycyl-L-methionylglycine (51529-34-1) → C48H57N3O10S

Guidance literature:

Multi-step reaction with 3 steps

1: aq. HCl / 20 °C

2: dimethylformamide / -10 - 20 °C

3: 58 percent / substituted Grubbs-type ruthenium carbene complex / CH₂Cl₂ / 18 h / 40 °C

With hydrogenchloride; substituted Grubbs-type ruthenium carbene complex; In dichloromethane; N,N-dimethyl-formamide;

DOI:10.1080/00397910701481146

Reference yield:

glycyl-L-methionylglycine (51529-34-1) + 4-carboxybenzophenone (611-95-0) → carbon dioxide (124-38-9,18923-20-1) + 4-carboxybenzophenone radical (128884-32-2) + benzophenone-4-carboxylic acid radical anion (79802-46-3) + C18H34N6O8S2(1+)

Guidance literature:

In water; at 22 ℃; Product distribution; Quantum yield; Rate constant; Irradiation; study the mechanism of 4-carboxybenzophenone-sensitized photooxidation investigated using nanosecond flash photolysis and steady-state photolysis at various pH values adjusted with phosphate buffer or NaOH;

DOI:10.1021/j100036a037

Downstream raw materials:

carbon dioxide

4-carboxybenzophenone radical

benzophenone-4-carboxylic acid radical anion