PhB(CH₂PPh₂)3Fe(CO)2(isocyanate)

Base Information

• Chemical Name: PhB(CH₂PPh₂)3Fe(CO)2(isocyanate)
• CAS No.: 847654-77-7
• Molecular Formula: C₄₈H₄₁BFeNO₃P₃
• Molecular Weight: 839.438
• Mol file: 847654-77-7.mol

Synonyms:PhB(CH₂PPh₂)3Fe(CO)2(isocyanate)

Chemical Property of PhB(CH₂PPh₂)3Fe(CO)2(isocyanate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of PhB(CH₂PPh₂)3Fe(CO)2(isocyanate)

There total 4 articles about PhB(CH₂PPh₂)3Fe(CO)2(isocyanate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

potassium cyanate (590-28-3) + PhB(CH2PPh2)3Fe(CO)2Cl (847654-78-8) → PhB(CH2PPh2)3Fe(CO)2(isocyanate) (847654-77-7)

Guidance literature:

In tetrahydrofuran; using Schlenk or glovebox techniques under N2 atm.; Fe complex and KNCO were stirred in THF for 24 h; volatiles removed (vac.); solid extd. (benzene); filtered over Celite; lyophilized; elem. anal.;

DOI:10.1021/ja0453073

Reference yield:

[PhB(CH2PPh2)3]FeCl (494843-61-7) → PhB(CH2PPh2)3Fe(CO)2(isocyanate) (847654-77-7)

Guidance literature:

Multi-step reaction with 2 steps

1: benzene

2: tetrahydrofuran

In tetrahydrofuran; benzene;

DOI:10.1021/ja0453073

Reference yield:

[[PhB(CH2PPh2)3Fe]2(μ-N)][Na(THF)5] + carbon monoxide (201230-82-2) → {[PhBP3Ph]Fe}(CO)2 (494843-67-3) + PhB(CH2PPh2)3Fe(CO)2(isocyanate) (847654-77-7)

Guidance literature:

In tetrahydrofuran; under N2 atm.; Fe nitride complex was dissolved in THF in NMR tube; soln. was frozen; N2 atm. was evacuated and replaced with 1 atm. of CO; NMR tube was shaken over 10 min; volatiles removed (vac.); not isolated; monitored by NMR and IR spectroscopy;

DOI:10.1021/ja0453073

upstream raw materials:

potassium cyanate

PhB(CH₂PPh₂)3Fe(CO)2Cl

carbon monoxide

[PhB(CH₂PPh₂)₃]FeCl